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悬浮区域熔炼法制备LaB_6单晶体与发射性能研究
  • 期刊名称:物理学报
  • 时间:0
  • 页码:517-523
  • 语言:中文
  • 分类:TN104.1[电子电信—物理电子学] O482.5[理学—固体物理;理学—物理]
  • 作者机构:[1]Key Laboratory of Advanced Functional Materials of Ministry of Education,College of Materials Science and Engineering,Beijing University of Technology, Inner Mongolia Key Laboratory for Physics and Chemistry of Functional Materials,College of Physics and Electron Information,Inner Mongolia Normal University
  • 相关基金:Project supported by the National Natural Science Foundation of China (Grant No. 50871002).
  • 相关项目:纳米LaB6晶粒尺度与场发射阴极性能关系规律研究
中文摘要:

Polycrystalline rare-earth hexaborides(NdxGd1-x)B6(x = 0,0.2,0.6,0.8,1) were prepared by the reactive spark plasma sintering(SPS) method using mixed powder of GdH2,NdH2 and B.The effects of Nd doping on the crystal structure,the grain orientation,the thermionic emission and the magnetic properties of the hexaboride were investigated by X-ray diffraction,electron backscattered diffraction and magnetic measurements.It is found that all the samples sintered by the SPS method exhibit high densities(> 95%) and high values of Vickers hardness(2319 kg/mm2).The values are much higher than those obtained in the traditional method.With the increase of Nd content,the thermionic emission current density increases from 11 to 16.30 A/cm2 and the magnetic phase transition temperature increases from 5.85 to 7.95 K.Thus,the SPS technique is a suitable method to synthesize the dense rare-earth hexaborides with excellent properties.

英文摘要:

Polycrystalline rare-earth hexaborides (NdxGdl-x)B6 (x = 0, 0.2, 0.6, 0.8, 1) were prepared by the reactive spark plasma sintering (SPS) method using mixed powder of GdH2, NdH2 and B. The effects of Nd doping on the crystal structure, the grain orientation, the thermionie emission and the magnetic properties of the hexaboride were investigated by X-ray diffraction, electron backscattered diffraction and magnetic measurements. It is found that all the samples sintered by the SPS method exhibit high densities (〉95%) and high values of Vickers hardness (2319 kg/mm2). The values are much higher than those obtained in the traditional method. With the increase of Nd content,the thermionic emission current density increases from 11 to 16.30 A/cm2 and the magnetic phase transition temperature increases from 5.85 to 7.95 K. Thus, the SPS technique is a suitable method to synthesize the dense rare-earth hexaborides with excellent properties.

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