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中文摘要：
本文以刚性间苯二酸（IP），对苯二酸（TP）及柔性丁二酸（SU）为桥联配体，溶剂热法合成了3个配合物[CdCrP）（DPQ）（H2O）k（1），[Cd（IP）（DPPZ）]n（2）和[Cd（su）（DPPZ）]。（3）（DPQ：毗嗪（2，3-f][1，10]菲咯啉，DPPZ=二毗啶[3，2-a：2′，3′-c]并吩嗪）。通过x射线单晶衍射分别测定了它们的结构。3个配合物均为单斜晶系，空间群分别为P21/c（配合物1和3）和c2／c（配合物2）。配合物荧光性质的表征表明，采用刚性二酸有利于配位聚合物荧光的增强。
英文摘要：
Three cadmium（H） dicarboxylate coordination polymers have been synthesized by solvothermal method： [Cd（TP）（DPQ）（H2O）], （1）, [Cd（IP）（DPPZ）]n （2） and [Cd（SU）（DPPZ）]n （3） （TP=terephthalate, IP=isophthalate, SU= succinate, DPQ=pyrazino[2,3-f][1,10]phenanthroline, DPPZ=dipyrido[3,2-a：2′,3′-c]phenzine）. Among them, 1 and 3 crystallize in the monoclinic space group P21/c, while 2 in C2/c. Luminescent studies show that, with the flexible dicarboxylate, the fluorescence intensity of 3 is much less than that of 1 and 2. CCDC： 725669, 1; 725667, 2; 725668, 3.
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