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Leaching kinetics of molybdenum from Ni-Mo ore in sulfuric acid solution with sodium peroxodisulfate as oxidant
  • ISSN号:0253-4320
  • 期刊名称:《现代化工》
  • 时间:0
  • 分类:TQ621.12[化学工程—精细化工] TD954[矿业工程—选矿]
  • 作者机构:[1]College of Physics and Mechanical & Electrical Engineering, Jishou University, Jishou 416000, China, [2]School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China, [3]College of Biology and Environmental Sciences, Jishou University, Jishou 416000, China
  • 相关基金:Project(51364009) supported by the National Natural Science Foundation of China; Project(JSU071302) supported by the Construct Program of the Key Discipline in Hunan Province,China; Project(2015JJ2115) supported by the Natural Science Foundation of Hunan Province,China
中文摘要:

The leaching kinetics of molybdenum from Ni-Mo ore in sulfuric acid solution with sodium peroxodisulfate was studied.The effects including leaching temperature, reaction time, particle size, stirring speed, and concentrations of sulfuric acid and sodium peroxodisulfate were investigated. The leaching process of molybdenum from Ni-Mo ore is controlled by the chemical reaction through the solid layer across the unreacted shrinking core. The apparent activation energy of the leaching of molybdenum is calculated to be 41.0 k J/mol and the leaching kinetics equation of molybdenum from Ni-Mo ore is expressed as1-(1-a)1/3=3405.7exp[-41030.0/(RT)]t.

英文摘要:

The leaching kinetics of molybdenum from Ni-Mo ore in sulfuric acid solution with sodium peroxodisulfate was studied.The effects including leaching temperature, reaction time, particle size, stirring speed, and concentrations of sulfuric acid and sodium peroxodisulfate were investigated. The leaching process of molybdenum from Ni-Mo ore is controlled by the chemical reaction through the solid layer across the unreacted shrinking core. The apparent activation energy of the leaching of molybdenum is calculated to be 41.0 k J/mol and the leaching kinetics equation of molybdenum from Ni-Mo ore is expressed as1-(1-a)1/3=3405.7exp[-41030.0/(RT)]t.

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期刊信息
  • 《现代化工》
  • 中国科技核心期刊
  • 主管单位:中国石油和化学工业联合会
  • 主办单位:中国化工信息中心
  • 主编:张立萍
  • 地址:北京安外小关街53号化信大厦B座703
  • 邮编:100029
  • 邮箱:zhanglp@cheminfo.gov.cn
  • 电话:010-64444095 64444090 64437104传
  • 国际标准刊号:ISSN:0253-4320
  • 国内统一刊号:ISSN:11-2172/TQ
  • 邮发代号:82-67
  • 获奖情况:
  • 2002年全国石油和化工行业优秀期刊评比一等奖和广...,1996年第二届全国优秀科技期刊一等奖,1992年北京市全优期刊奖,第一届、第三届国家期刊奖,建国60周年有影响力期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:26705