论述了近年来国际上较为活跃的超分子化学领域,在配位化合物的分子设计和性质研究等方面的重要应用.依据超分子自组装与配位化合物的相关理论及研究状况,紧密结合本研究组的近期工作和最新进展,分析探讨了氨基硫脲系列超分子配合物的分子设计和组装,及其组成-结构-非线性光学性质,为后续新型功能性超分子配合物的设计合成提供必要的基础.
The investigations of recent progress in the fields of design and synthesis of supramolecular coordination compounds, as well as their applications, are reviewed in the text. As new potential functional materials, supramolecular coordination compounds containing thiosemicarbazide have been synthesized via molecular design and spontaneous assembly, and their composition - structure - nonlinearity relationships are discussed in this thesis. All the achievements for our research work have been carried out in order to design and synthesize new functional complex with novel structure effectively.