中文摘要：

在流动反应管中,利用高纯N2空心阴极放电制备活性氮,研究了活性氮与溴分子碰撞反应得到的发射光谱.在540～800nm波段观察到了较强的NBr（b^1Σ^＋→X^3Σ^-）跃迁发射谱,在292nm处观察到了Br2（D＇→A＇）辐射跃迁.实验结果表明,得到的NBr（b^1Σ^＋）显示出了非弛豫的发射特征,最高振动能级为ν＇=9.激发态的NBr（b^1Σ^＋）是由活性氮中的N（^2P）原子与Br2直接反应生成的.

英文摘要：

Active nitrogen has been prepared by hollow-cathode discharge of high pure nitrogen in a flow reactor, and the emission spectra obtained in the reaction of active nitrogen with Br2 have been studied. The strong emission spectra of NBr（b^1Σ^＋→X^3Σ^- ） in the range of 540-800 nm have been observed when bromine is added to a stream of active nitrogen, and the spectra around 292 nm is ascribed to the transition of Br2（D＇→A＇）. The results show that the excited state NBr（b^1Σ^＋） are found to exhibit vibrationally unrelaxed emissions （from up to v＇=9）, and the electronically excited NBr（b^1Σ^＋） is formed directly by the reaction of excited nitrogen atom N（^2p） with Br2.