Low-valent titanium induced reductive cyclization of nitro compounds and aliphatic ketones:facile synthesis of 3,4-dihydro-(2H) -1,2,4-benzothiadiazine-1,1-dioxides
- ISSN号:1001-604X
- 期刊名称:《中国化学:英文版》
- 分类:O621.25[理学—有机化学;理学—化学]
- 作者机构:Department of Chemistry, Zhejiang University(Campus Xixi), Hangzhou, Zhejiang 310028, China, China Department of Chemistry, Hunan Jishou University, Jishou, Hunan 416000, China, China Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
- 相关基金:Project supported by the National Natural Science Foundation of China (No. 29872010);Natural Science Foundation of Zhejiang Province, China
关键词:
Nitro, compounds, KETONES, REDUCTIVE, CYCLIZATION, samarium, titanium, tetrachloride., Nitro compounds, ketones, reductive cyclization, samarium, titanium tetrachloride
中文摘要:
The intermolecular reductive cyclization of o-nitrobenzene-sulfonamides with aliphatic ketones induced by TiCl4/Sm system was studied and a series of 3,3-disubstituted-3,4-dihydro-(2H)-1,2,4-benzothiadiazine-1,1-dioxides were synthesized in moderate to high yields under mild and neutral conditions.
英文摘要:
The intermolecular reductive cyclization of o-nitrobenzene-sulfonamides with aliphatic ketones induced by TiCl4/Sm system was studied and a series of 3, 3-disubstituted-3,4-dihydro(2H)-1,2, 4-benzothiadiazine-1,1-dioxides were synthesized in moderate to high yields under mild and neutral conditions.