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熔制温度对铋离子掺杂钡铝硅酸盐玻璃发光性能的影响
  • ISSN号:1000-7032
  • 期刊名称:《发光学报》
  • 时间:0
  • 分类:O482.31[理学—固体物理;理学—物理] TQ171[化学工程—玻璃工业;化学工程—硅酸盐工业]
  • 作者机构:[1]浙江大学硅材料国家重点实验室,浙江杭州310027
  • 相关基金:国家自然科学基金(50672087);国家科技部“973”(2006CB806000b)资助项目
中文摘要:

研究了熔制温度对铋离子掺杂钡铝硅酸盐玻璃发光性能的影响。当用紫外光和808nm的激光二极管激发时,分别在425nm和1330nm附近观察到可见和宽带红外发光。可见荧光的发射强度随着熔制温度的升高逐渐下降,而红外发光强度随着熔制温度的升高先是增强然后减弱。对光致发光的机理进行了探讨。

英文摘要:

The influence of melting temperature on the luminescence properties of bismuth-doped barium aluminosilicate glasses was studied. Bismuth-doped barium aluminosilicate glasses were prepared at various melting temperatures. Absorption spectra, visible luminescence, infrared luminescence and fluorescent lifetime of the infrared luminescence of the glass samples were measured. There were two absorption peaks, one strong peak is at about 320 nm, and the other is at about 450 nm. The absorbance increased with increasing melting temperature. Visible luminescence was observed at about 420 nm, 440 nm and 475 nm when excited by 380 nm ultraviolet light. The infrared luminescence was observed at about 1 330 nm when excited by 808 nm laser diode (LD). The intensity of the visible luminescence decreased with increasing melting temperature, while the intensity of the infrared luminescence increased at first, and then decreased with a further increase of melting temperature. But the fluorescent lifetime of the infrared luminescence decreased at first, and then increased with a further increase of melting temperature. The broadband infrared luminescence originates from bismuth ions, but is not due to high valence state ion of bismuth as suggested by Fujimoto et al. We attribute the visible and infrared luminescence to Bi3+ and Bi ~ , respectively. The melting temperature may greatly influence the broadband infrared luminescence of bismuth-doped glasses. It is necessary to choose best melting temperature for the preparation of bismuth-doped glasses.

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期刊信息
  • 《发光学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国物理学会发光分会 中国科学院长春光学精密机械与物理研究所
  • 主编:申德振
  • 地址:长春市东南湖大路3888号
  • 邮编:130033
  • 邮箱:fgxbt@126.com
  • 电话:0431-86176862
  • 国际标准刊号:ISSN:1000-7032
  • 国内统一刊号:ISSN:22-1116/O4
  • 邮发代号:12-312
  • 获奖情况:
  • 物理学类核心期刊,2000年获中国科学院优秀期刊二等奖,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:7320