采用静电纺丝法制备PVP/Zn(CH3COO)2/Cu(NO3)2复合纤维,经烧结得到ZnO/CuO纳米复合纤维。对烧结前后的纤维形貌、纯度和晶型用热重分析仪(TG),X射线能谱仪(EDS),傅里叶红外光谱仪(FTIR),X射线衍射仪(XRD)和场发射扫描电镜(FE-SEM)来进行表征。用紫外-可见分光光度计(UV-vis)来表征ZnO/CuO纳米复合纤维对亚甲基蓝溶液的光催化降解情况。结果显示:乙酸锌与硝酸铜的质量比为10∶1时,复合纤维在700℃时烧结剩余样品,其光催化性能相对较好。
PVP/Zn(CH3COO)2/Cu(NO3)2 composite nanofibers are prepared by electrospinning,and ZnO/CuO composite nanofibers are successfully obtained by high temperature sintering of those above composite nanofibers.Field-emission scanning electron microscope(FE-SEM),thermal gravimetric analysis(TG),energy dispersive spectroscopy(EDS),fourier transform infrared spectroscopy(FTIR) and X-ray diffraction(XRD) are used to characterize fibers before and after sintering.The photocatalytic activity of ZnO/CuO composite nanofibers is investigated using ultraviolet–visible Absorbance by following the photodegradation of methylene blue.When the composite fibers of zinc acetate and copper nitrate complex mass ratio being 20∶1 is sintered at 700 ℃,it is found the photocatalytic efficiencies of the remaining sample at this point are proved to be the highest by monitoring the photodegradation of methylene blue.