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木屑高温水蒸气气化制备合成气研究
  • ISSN号:0254-0096
  • 期刊名称:《太阳能学报》
  • 时间:0
  • 分类:TK6[动力工程及工程热物理—生物能]
  • 作者机构:[1]中国林业科学研究院林产化学工业研究所, 生物质化学利用国家实验室, 国家林业局林产化学工程重点开放性实验室, 江苏省生物质能源与材料重点实验室,南京210042, [2]中国林业科学研究院林业新技术研究所,北京100091
  • 相关基金:林业公益性行业科研专项(200904062);国家自然科学基金(30972318);中央级公益性科研院所基本科研业务费专项(CAFINT2009K02)
中文摘要:

在常压固定床反应器中进行木屑高温水蒸气气化制取合成气研究。分别在750~1000℃温度和0.32—1.02g/min水蒸气流量下进行实验,反应时间为10min。主要研究反应温度和水蒸气流量对碳转化率、合成气产率及合成气组分的影响。研究结果表明,木屑水蒸气气化具有很高的反应活性,合成气产率在0.81—1.74L/g之间;反应温度和水蒸气流量对碳转化率和合成气热值及组分影响显著;在反应温度950℃,水蒸气流量0.67g/min时,碳转化率达到最高值99.47%;合成气主要由H2、CO、CO2、CH4及少量CnHm组成,其中(H:+CO)比例达到63%~75%,合成气热值在10.5—11.5MJ/m。之间,HdCO比在1.0—2.3之间。

英文摘要:

High temperature steam gasification of sawdust was studied at atmospheric pressure in a fixed bed reactor. Experiments were carried out at 750,800, 850, 900, 950 and 1000 ℃ with different steam flow rates in the range of 0.32 to 1.02 g/min and a reaction time of 10 min. The effects of temperature and steam flow rate on carbon conversion, synthesis gas yield, heat value and its compositions were mainly studied. It has been found that steam gasification of sawdust was highly reactive, particularly at high temperature; synthesis gas yield was in the range of 0.81-1.74 L/g. The results showed that steam flow rate and temperature have strong effects on the carbon conversion, synthesis gas yield, heat value and its compositions. The conversion of this char was maximum (99.47%) at 950 ℃ with steam flow rates of 0.67 g/rain. The product gas obtained was mainly a mixture of H2, CO, COs, and CH4. Under the present reaction conditions, synthesis gas (H~ + CO) produced by steam gasification of char was in the range of 63%-75%, The low heating value of the product gas was in the range of 10.5-11.5 MJ/m3, and the H2/CO molar ratio was about 1.0-2.3. The results suggest that there is a strong potential for producing synthesis gas from steam gasification of sawdust.

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期刊信息
  • 《太阳能学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科协
  • 主办单位:中国可再生能源学会
  • 主编:
  • 地址:北京市海淀区花园路3号
  • 邮编:100083
  • 邮箱:
  • 电话:010-62001037
  • 国际标准刊号:ISSN:0254-0096
  • 国内统一刊号:ISSN:11-2082/TK
  • 邮发代号:2-165
  • 获奖情况:
  • 1992年北京新闻出版局评比全优期刊奖,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:20390