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石墨烯纤维的湿法纺丝制备及性能研究术
  • ISSN号:1001-0564
  • 期刊名称:《北京服装学院学报:自然科学版》
  • 时间:0
  • 分类:TQ340.64[化学工程—化纤工业]
  • 作者机构:[1]北京服装学院材料科学与工程学院,服装材料研究开发与评价北京市重点实验室,北京100029, [2]北京市建筑工程研究院有限责任公司,北京100039
  • 相关基金:国家自然科学基金项目(21544002);北京市教委科技重点项目(KZ201410012017);北京市科技新星计划(XX2014033);北京服装学院高水平人才交叉培养“实培计划”项目(NHFZ2016065/001)
中文摘要:

本文利用改进的Hummers法制备了氧化石墨烯悬浮液,探索了纺丝液浓度、凝固浴中溶质与溶剂种类以及配比等条件对纺丝的影响.采用湿法纺丝纺出长达40多厘米的氧化石墨烯纤维.采用氢碘酸对氧化石墨烯纤维进行化学还原,得到电导率达117.74S/era的石墨烯纤维,可作为导线运用.其机械性能也得以增强,能够打结,断裂强度达到0.82cN/dtex,断裂伸长率为4.17%,弹性模量为30.75cN/dtex,断裂强度约为棉纤维的三分之一,具有一定的实用性.

英文摘要:

Graphene has attracted more and more research attentions due to its excellent electrical, thermal conductivity and mechanical properties. The two-dimensional single-layer film of graphene is the thin nest nanomaterial with the highest conductivity and mechanical strength. The one-dimen- sional graphene fibers prepared by wet spinning, which combine the high conductivity of grapheme with the flexibility and spinnability of conventional fiber materials, have wide application prospects in the field of intelligent textiles. In this paper, the suspension of graphene oxide was prepared by an improved Hummers method. The influence of the spinning solution concentration and the type of sol- ute and solvent in the coagulation bath on the spinning was studied. Graphene oxide fibers with length up to 44 cm were obtained by wet spinning, which were then reduced with hydroiodic acid to get graphene fibers. These fibers have an electrical conductivity of 117 S/cm and can be used as electricwires. Mechanical property measurement indicates that the graphene fibers have a breaking strength of O. 82 cN/dtex, which is about 1/3 of cotton fibers, a breaking elongation of 4.17% and an elastic modulus of 30.75 cN/dtex. The graphene fibers can be knotted as normal fibers and showing good prospects for practical applications.

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期刊信息
  • 《北京服装学院学报:自然科学版》
  • 北大核心期刊(2014版)
  • 主管单位:北京市教育委员会
  • 主办单位:北京服装学院
  • 主编:廖青
  • 地址:北京市朝阳区和平街北口樱花路甲2号
  • 邮编:100029
  • 邮箱:
  • 电话:010-64289812
  • 国际标准刊号:ISSN:1001-0564
  • 国内统一刊号:ISSN:11-2523/TS
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国剑桥科学文摘,英国世界纺织文摘,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2014版)
  • 被引量:1807