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Absolute Configuration of the Phenylpropanoid Isolated from Peperomia tetraphylla
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 时间：0
  • 分类：O626.32[理学—有机化学;理学—化学] X832.02[环境科学与工程—环境工程]
  • 作者机构：[1]School of Chemistry and Material Sciences, Heilongjiang University, Harbin, Heilongjiang 150080, China, [2]State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
  • 相关基金：This work was supported by the National Natural Science Foundation of China （21172247, 21032002） and the Chinese Academy of Sciences.
作者： Yanchao Yu[1,2], Xiaowei Lu[2], Wenju Wu[1,2], Yikang Wu[2], Bo Liu[1]
关键词： 天然产物, 酚类, 型综合, 多年生草本植物, 酯, 绝对构型, 光谱数据, 兜兰属, esters, alkylation, natural products, stereochemistry, phenols
中文摘要：

二最近识别的自然酉分的 homobenzyl 酉旨，从 Phragmipedium 孤立 calurum (一朵兰花) 和 Eupatorium fortunei TURCZ (在 Asteraceae 家庭的长期的植物) 分别地，在 enantiopure 形式被综合。由光旋转为的比较合成并且自然样品，为自然产品的绝对配置可靠地被分配。合成也启用密切相关的自然 homobenzyl 白酒的绝对配置的建立并且为二另外的自然 homobenzyl 酉旨为第一次提供了完全的物理、分光镜的数据。

英文摘要：

Two recently identified natural phenolic homobenzyl esters, isolated from Phragmipedium calurum （an orchid） and Eupatoriumfortunei TURCZ （a perennial herb in the Asteraceae family）, respectively, were synthesized in enantiopure forms. By comparison of the optical rotations for the synthetic and the natural samples, the absolute configurations for the natural products were reliably assigned. The synthesis also enables establishment of the absolute configuration of a closely related natural homobenzyl alcohol and provided for the first time complete physical and spectroscopic data for two other natural homobenzyl esters.

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期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175