用气相色谱质谱联用方法对太原市小店污灌区地表水中2种内分泌干扰物壬基酚(4-NP)、辛基酚(4-t-OP)以及4-NP前体壬基酚聚氧乙烯醚(NPEOs)的含量进行检测,结果表明地表水中3种污染物残留水平分别为0.83-47.68μg·L^-1(均值为5.92μg·L^-1)、ND-2.05μg·L^-1(均值0.19 μg·L^-1)和1.21—22.21μg·L^-1(均值为7.49μg·L^-1).沿着东干渠和北张退水渠水流方向,NPEOs逐渐升高,沿着太榆退水渠水流方向,4一NP逐渐升高,表明地表水中污染物浓度的分布受人类活动的影响较大.在退水渠。4-NP和NPEOs浓度相对较高,且二者呈现显著正相关(r=0.967,P=0,00〈0.01),证实了污水灌溉后一部分NPEOs发生了降解.该区域内水体中2种内分泌干扰物生态风险相对较强.
Gas chromatography-mass spectrometry (GC-MS) was used to analyze the distribution characteristics of two endocrine disrupting chemicals ( EDCs ), nonylphenol ( 4-NP ), and octylphenol (4-t-OP), together with the precusor, nonylphenol polyethoxylates (NPEOs), in surface water of Xiaodian sewage irrigation area.The results showed that the concentration of the three pollutants ranged from 0.83 to 47.68 μg·L^-1( mean 5.92μg·L^-1 ), 0 to 2.05 μg·L^-1 ( mean 0.19μg·L^-1 ) and 1.21 to 22.21μg·L^-1 ( mean7.49μg·L^-1 ) , respectively. Along the Beizhang drainage and the East Main channel, the content of NPEOs increased, while the level of 4-NP increased alone the Taiyu drainage. This was attributed to the influence from anthropogenic activities. In addition,4-NP and NPEOs prevailed over two Drainages and both pollutants presented significant positive correlation, which suggests partial degradation of NPEOs in wastewater after irrigation in the area.