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Density and viscosity of aqueous solution of K2CrO4/KOH mixed electrolytes
  • ISSN号:1003-6326
  • 期刊名称:Transactions of Nonferrous Metals Society of China
  • 时间:0
  • 页码:32-36
  • 分类:X703[环境科学与工程—环境工程]
  • 作者机构:Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Ac ademy of Sciences
  • 相关基金:Project(2007CB613501) supported by the National Basic Research Program of China;project(50904058) supported by the National Natural Science Foundation of China;project(2006BAC02A05) supported by National Science and Technology Pillar Program of China
  • 相关项目:碱金属铬酸盐低温氢还原法制备氧化铬新工艺的应用基础研究
中文摘要:

The physicochemical properties are very important in theoretical investigation of aqueous electrolyte solution and industrial design of hydrometallurgical processes. In the green hydrometallurgical process of chromite ore with sub-molten salt medium of KOH, the ternary system of KOH+K2CrO4+H2O is essential to process control and industrial operation. In order to satisfy the needs of both fundamental research and industrial application, the dynamic viscosity (η) and density (ρ) of mixed aqueous electrolyte solution of KOH and K2CrO4 were measured over a temperature range from 15 to 60 ℃ by using Ubbelohde-type capillary viscometers and a series of densimeters, respectively. The temperature is controlled to an accuracy of ±0.01 ℃ throughout the experiment with thermostat. The dynamic viscosity and density of the ternary systems are performed as functions of chromate and hydroxide concentration and temperature. The regression equations for viscosity and density are obtained with a least-square method and the calculated values are consistent well with the experimental data. The semi-empirical equation obtained will be helpful and instructive to industrial application.

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期刊信息
  • 《中国有色金属学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国有色金属学会
  • 主编:黄伯云
  • 地址:中国长沙中南大学
  • 邮编:410083
  • 邮箱:f-xsxb@csu.edu.cn
  • 电话:0731-88830949
  • 国际标准刊号:ISSN:1003-6326
  • 国内统一刊号:ISSN:43-1239/TG
  • 邮发代号:42-317
  • 获奖情况:
  • 国家“双百”期刊,第二届全国优秀科技期刊评比二等奖,中国有色金属工业总公司优秀科技期刊一等奖
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  • 被引量:1159