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中文摘要：
碳纳米管是具有一维纳米结构的新型纳米材料,具有许多独特的物理、化学性质.卟啉对可见光具有强烈吸收,其大π共轭体系使其具有良好的电子给予能力,可作为人工光合作用体系的光捕捉单元.将具有电子接受能力的碳纳米管与卟啉结合起来,通过卟啉对碳纳米管进行共价和非共价修饰,可以改善碳纳米管在溶剂中的溶解分散性能,同时实现卟啉和碳纳米管之间有效的电子传递,形成具有独特光电和光学性质卟啉-碳纳米管复合物.该类物质具备良好的应用前景,是碳纳米管和卟啉研究中的热点.就近年来该类复合物的构筑方法及性质研究等方面的进展进行了综述.
英文摘要：
Carbon nanotubes are novel nano-materials with one-dimentional nanostructure.They have many unique physical and chemical properties.Porphyrin has strong absorption in visabal light region.The large π conjugated system made it a good electron donor and light harvest unit for artifical photosynthetic systems.The combination of electron donor carbon nanotubes with porphyrin and the covalent and non-covalent porphyrin modification of carbon nanotubes can improve solubility and dispersibility of carbon nanotubes in solvent and carry out effective electron transfer between them to form porphyrin-carbon nanotube hybrid systems with unique photoelectric and optical properties.These kind of hybrid systems have a good application prospect and are hot point in related research fields.In this review,recent progress of the construction and properties of these hybrid systems is summarized.
同期刊论文项目
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Synthesis of a Series of meso-substituted Zinc Porphyrin Derivatives and their Assembly Dyad with Fu
Covalently b-cyclodextrin modified single-walled carbon nanotubes: a novel artificial receptor synth
Dynamic Assembly Inclusion Complexes of Tweezer-type Bis(zinc porphyrin) with 5,15-Di(4-pyridyl)porp
Dynamic Assemblies and Photophysical Changes of Zinc Porphyrin Dimer Regulated by N-Containing Ligan
A Nanohybrid Material of SWNTs Covalently Functionalized with Porphyrin for Light Harvesting Antenna
A Novel Light Harvesting System: Synthesis, Characterization, and Photophysical Properties of Covale
A Novel Soluble Tin(IV) Porphyrin Modified Single-Walled Carbon Nanotube Nanohybrid With Light Harve
Fluorescence Switch of Tweezers-type Bis(Zinc Porphyrin) Complex Regulated by Double Guests of Cu+ I
Enhanced Optical Limiting Effects in Porphyrin-Covalently Functionalized Single-Walled Carbon Nanotu
Synthesis and Characterization of the Monomeric Vicinal Dianion and the Aluminum and Lithium Derivat
Catalytic enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by a
Synthesis, structures and norbornene polymerization behavior of bis(aryloxide-N-heterocyclic carbene
A n-BuLi-Mediated Expeditious and Stereoselective Ring-Opening Rearrangement of Aryl Methylenecyclop
Effect of lower-rim alkylation of p-sulfonatocalix[4]arene on the thermodynamics of host–guest compl
Molecular binding behaviours of bile salts by bridged and metallobridged bis(β-cyclodextrin)s with n
Highly Diastereoselective Gold- or Copper-Catalyzed Formal [4+3] Cycloaddition of 1-(1-Alkynyl) Cycl
Reactions of the doubly bridged bis(cyclopentadienyl) dinuclear molybdenum complex (Me2C)(Me2Si)[((5
Artemether/hydroxypropyl-(-cyclodextrin host–guest system: characterization, phase-solubility and in
Inclusion complexes of bisphenol A with cyclomaltoheptaose ((-cyclodextrin): solubilization and stru
Synthesis of l-cystine modified cyclodextrin monomers and dimers with primary-side versus secondary-
Critical stereocontrol by inter-amino distance of supramolecular photocyclodimerization of 2-anthrac
A polymeric pseudorotaxane constructed from cucurbituril and aniline, and stabilization of its radic
A highly regioselective tandem 1,3-dipolar cycloaddition of cyclopropene 1,1-diesters and nitrile ox
Colorimetric Sensor and Inverse Fluorescent Behavior of Anions by Calix[4]arene Possessing Imidazo[4
Enantioselective synthesis of chiral (-aryloxyalcohols by ruthenium-catalyzed ketone hydrogenation v
Highly enantioselective hydrogenation of (-arylmethylene cycloalkanones catalyzed by iridium complex
The Synthesis of A Novel Bisimidazolium Branched Zinc Metallporphyrin and Its Recognition for Halide
N-Heterocyclic Carbene-Catalyzed Domino Ring-Opening/Redox Amidation/Cyclization Reactions of Formyl
ntramolecular Si?Si Bond Activation by the Iron Carbonyl Unit in an (η4-Silole)tricarbonyliron Compl
Synthesis and Properties of Structural Variants of the Si–Si Bridged Bis(cylcopentadienyl)tetracarbo
Effect of (-Cyclodextrin Charge Type on the Molecular Recognition Thermodynamics of Reactions with (
Simply modified chiral diphosphine: catalyst recycling via non-covalent absorption on carbon nanotub
Molecular aggregation behavior of perylene-bridged bis((-cyclodextrin) and its electronic interactio
A Reversible Luminescent Lanthanide Switch Based on a Dibenzo[24]-Crown-8- Dipicolinic Acid Conjugat
Quinolinotriazole-β-cyclodextrin and its adamantanecarboxylic acid complex as efficient water-solubl
Sulfonium alkylation followed by 'click' chemistry for facile surface modification of proteins and t
Cyanine Dye-Based Chromofluorescent Probe for Highly Sensitive and Selective Detection of Cyanide in
Reactions of dihydrooctamethyl-s-indacene and 1,2,3,4,7-pentamethylindene with Ru3(CO)12: Intramolec
Design, Synthesis and 3D-QSAR Analysis of Novel 1,3,4-Oxadiazol-2(3H)-ones as Protoporphyrinogen oxi
A colorimetric and "turn-on" fluorescent chemosensor for Zn(II) based on coumarin Shiff-base derivat
Supramolecular assembly of perylene bisimide with β-cyclodextrin grafts as a solid-state fluorescenc
Total Synthesis of (±)-Bruguierol A via an Intramolecular [3+2] Cycloaddition of Cyclopropane 1,1-Di
Organocatalytic Three-Component Reactions of Pyruvate, Aldehyde and Aniline by Hydrogen-Bonding Cata
Reactions of (Me2C)(Me2Si)[((5-C5H3)Mo(CO)3]2 with nitrile and subsequent cleavage of the C-N triple
Unexpected reactions of (Me2C)(Me2Si)[((5-C5H3)Mo(CO)3]2 with diazoalkane and carbon disulfide: Acti
Synthesis and reactivity of 2-(tert-butylcyclopentadienyl)-indenyl dinuclear ruthenium complex [?5:?
Hydride, Hydrogen Atom, Proton and Electron Transfer Driving Forces of Various Five-membered Heteroc
Access to B=S and B=Se double bond via sulfur and selenium insertion into a B-H bond and hydrogen mi
Effective enlargement of fluorescence resonance energy transfer of poly-porphyrin mediated by β-cycl
Homologous and heterologous interactions between catalytic and regulatory subunits of Escherichia co
Noncovalent functionalization of single-walled carbon nanotube by porphyrin: dispersion of carbon na
Controlled/“living” radical polymerization of methyl methacrylate catalyzed by CpCo(I) complexes con
Chiral ruthenium-SDPs/diamine complexes-catalyzed enantioselective hydrogenation of (-alkyl arylacet
Bifunctional Catalysis of Morita-Baylis-Hillman (MBH) Reaction with Chiral Primary-Tertiary Diamine:
Arginine Catalyzed Direct Aldol Reactions in Pure Water: An Environmentally Friendly Reaction System
Highly enantioselective and diastereoslective synthesis of chiral amino alcohols by ruthenium-cataly
Solid-state supramolecular architectures by p-sulfonatocalix[5]arene with bispyridinium derivatives:
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