摘要研究了超声波(100W100kHz)对电沉积c0.Ni合金层的结构、形貌和性能的影响。结果表明:施加超声波可有效降低电沉积过程中浓差扩散的影响,促进阴极表面与镀液界面间的电子转移。超声波可降低Co-Ni合金层的Co含量并细化晶粒,使Co-Ni合金层更为平整。超声波影响Co-Ni合金层结构和形貌,可提高Co-Ni合金层的硬度以及在3.5%NaCl溶液中的耐腐蚀性。
The effects of ultrasound agitation (100 W, 100 kHz) on the structure, morphology and prop- erties of electrodeposited Co-Ni alloy coatings were investigated in this paper. The result shows that: when ultrasonic agitation was used during the alloy coating electrodeposition, the concentration diffusion was effectively reduced, and the electron transfer between the cathode/solution interface was also pro- moted. Ultrasound agitation leads to the increase of Co content in alloy coating. The Co-Ni alloy coating deposited under ultrasound agitation is more fine-grained and uniform. The ultrasound agitation can lead to the enhancement of hardness and corrosion resistance properties of Co-Ni alloy coatings.