在复合引入不同比例Al粉、Si粉(Al粉、Si粉的组合分别为2%(w)Al+3%(w)Si,3%(w)Al+2%(w)Si,4%(w)Al+1%(w)Si)的Al2O3-ZrO2-C材料中进一步外加质量分数分别为0、1%、2%的SiO2微粉,经配料、混练、成型、烘干后,在埋炭(煤焦炭)气氛中分别于800、1000、1200、1300和1400℃保温3h煅烧,然后对烧后试样进行三点弯曲试验,并测定烧后试样的平均孔径,分析烧后试样的显微结构。结果表明:1)对于含不同比例Al粉和Si粉的Al2O3-ZrO2-C材料,SiO2微粉的引入使其经1200oC或更高温度煅烧后的抗折强度、弹性模量和韧性提高,平均孔径减小;2)显微结构分析发现,含有SiO2微粉的试样中,A1N和(或)SiC晶须发育良好并且分布均匀,孔径细小,从而优化了材料力学性能。
Varied additions (0,1% ,and 2%) of microsilica powder were added in Al2O3-ZrO2-C refractory materials with different additions of metal AI and Si composite powders (2%Al +3%Si,3%Al +2%Si,4%Al + 1%Si). Specimens preparation strictly followed batching, mixing, pressing, curing, and firing in coke bed at 800,1000,1 200, 1 300 and 1 400℃ for 3 h, respectively. The three-point bending strength tests of fired specimens were carried out. Also the microstructure and pore size distribution of specimens were observed and analyzed. The results show that: (1)the introduction of microsilica can increase MOR,elastic modules,and toughness of the specimens fired at 1200 ℃ or higher temperatures, and decrease average pore size; (2) mechanical properties of the specimens with microsilica can be improved remarkably,which is attribu- ted to well-developed and evenly-distributed AIN and/or SiC whiskers with smaller average pore size in microstructure.