为了解固体电解质脱氧的内部机理,对氧化锆固体电解质电池短路脱氧过程中的外电路电压随时间的变化进行了研究.通过电池电动势与时间关系的数学模型,得出外电路电压与熔池中氧含量的关系,从而根据外电路电压可以预测脱氧反应进行的程度.结果表明,实验数据与模型结果一致.
In order to understand the mechanism of short-circuited deoxidization, an experiment was designed and performed for measuring the relation between the open circuit voltage of a deoxidization device and the process time. A theoretical formula was applied to this process so that the open circuit voltage could predict the limit of deoxidization reaction. The experiment results show that this experiment and theoretical analysis are successful.