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不同铝添加量对镁合金显微组织及大气腐蚀行为的影响
  • ISSN号:1005-4537
  • 期刊名称:《中国腐蚀与防护学报》
  • 时间:0
  • 分类:TG174.31[金属学及工艺—金属表面处理;金属学及工艺—金属学]
  • 作者机构:[1]哈尔滨工程大学材料科学与化学工程学院,哈尔滨150001, [2]中国科学院金属研究所金属腐蚀与防护国家重点实验室,沈阳110016, [3]内蒙古工业大学材料学院,呼和浩特010051
  • 相关基金:国家自然科学基金(50571105)
中文摘要:

利用SEM、EDAX、XRD等技术分析3种不同Al添加量的镁合金的显微组织和相结构,经实验室模拟金属大气腐蚀实验后观察其腐蚀形貌。结果表明,随着Al含量的增加,Mg-Al合金中β相(Mg17Al12)的数量明显增加;不存在β相的镁合金表面腐蚀产物较少,基体腐蚀较浅,存在β相的镁合金表面腐蚀产物较多,基体出现较深的腐蚀坑;β相的数量与分布的不同是镁合金腐蚀形貌存在差异的主要原因。

英文摘要:

Microstructure and phase constituent of magnesium-aluminum alloys adding different aluminum content (3.4 mass%, 9.3 mass%, 20.7 mass%)were investigated utilizing the scanning electron microscopy (SEM) equipped with energy-dispersive analysis of X-ray(EDAX) and X-ray diffraction (XRD).The influence of microstructure on the corrosion morphologies was observed after corrosion tests in laboratory simulated atmosphere. The results indicated that magnesium-aluminum alloys with different aluminum content in the atmospheric environment had different corrosion behavior due to amount and distribution of the/3 phase (Mg17TAl12). Mg-3Al alloy was approximately single-phase alloy,while Mg-9A] alloy and Mg-21Al alloy were two-phase alloys.There were more β phase in Mg-21Al alloy than in Mg-9Al alloy because of its higher aluminum content.Mg-3Al alloy exhibited better atmospheric corrosion resistance than Mg-9Al alloy and Mg-21Al alloy. There were fewer corrosion products on the surfaces of Mg-3Al specimens, while severe corrosion was found to take place in both Mg-9Al alloy and Mg-21Al alloy due to the presence of the β phase in them. More specifically,it was discovered that due to the absence of the couple-actuation of β phase,the corrosion of single-phase alloy Mg-3Al may be attributed solely to the pitting caused by high concentration of Cl^- near the NaCl deposits. However, with Mg-9Al alloy and Mg-21Al alloy,a more important factor for corrosion is the presence of β phase. Under couple-actuation of the negative of β phase, a phase causes a corrosion along the depth extent.

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期刊信息
  • 《中国腐蚀与防护学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科技协会
  • 主办单位:中国腐蚀与防护学会 中国科学院金属研究所
  • 主编:柯伟
  • 地址:沈阳市文化路72号
  • 邮编:110016
  • 邮箱:jcscp@imr.ac.cn
  • 电话:024-23971819
  • 国际标准刊号:ISSN:1005-4537
  • 国内统一刊号:ISSN:21-1474/TG
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国剑桥科学文摘,英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:7982