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生物沥浸法去除猪粪中重金属和提高其脱水性能研究
  • ISSN号:0253-2468
  • 期刊名称:环境科学学报
  • 时间:0
  • 页码:388-394
  • 分类:X705[环境科学与工程—环境工程]
  • 作者机构:[1]南京农业大学资源与环境科学学院环境工程系,南京210095
  • 相关基金:国家高技术研究发展计划(863)项目(No.2009AA06Z317); 国家自然科学基金项目(No.20977048)
  • 相关项目:生物酸化、次生矿物形成与生物絮凝耦合效应提高污泥脱水性能的作用与机理
中文摘要:

采用复合嗜酸性硫杆菌,通过摇瓶试验研究了不同Fe^2+添加量下生物沥浸对含固率为3%的猪粪中重金属的去除和脱水性能的影响.同时,考察了不同处理的pH、氧化还原电位(ORP)、Fe^2+、Fe^3+、总Fe、Cu、Zn、比阻和毛细吸水时间(CST)的变化.结果表明,采用生物沥浸技术能有效地去除猪粪中的重金属,随着Fe^2+添加量的增加,猪粪中重金属的去除率呈上升趋势,其中,4g·L^-1Fe^2++2g·L^-1S0+接种嗜酸性硫杆菌的处理效果最好,沥浸结束后对Cu和Zn的去除率分别达到了87.3%和91.9%,重金属Zn先于Cu从猪粪中溶出.研究发现,沥浸结束后,猪粪的比阻和CST与原始猪粪相比大幅度降低,且随着Fe^2+添加量的增加其脱水性能也得到提高,在添加2g·L^-1S0和接种嗜酸性硫杆菌的情况下,添加4g·L^-1Fe^2+和5g·L^-1Fe^2+的处理,其脱水性能较原始猪粪分别提高了117和205倍.采用生物沥浸技术处理猪粪,可去除其中的重金属,改善其脱水性,提高猪粪资源化再利用的价值,这为猪粪的资源化利用提供了一种全新的途径.

英文摘要:

Removal of heavy metals and dewaterability of pig slurry during bioleaching were investigated through batch experiments with co-inoculation of two acidophilic thiobacilli (Acidithiobacillus thiooxidans TS6 and Acidithiobacillus ferrooxidans LX5) and the addition of Fe^2+ as energy source. During bioleaching,dynamic changes of pH,ORP,Fe^2+,Fe^3+,total Fe,Zn,Cu,and dewaterability (expressed as specific resistance γ or Capillary Suction Time CST) of pig slurry were monitored periodically. Results showed that bioleaching process could solubilize pig slurry-borne heavy metals. Moreover,higher addition of Fe^2+ led to higher removal efficiency of heavy metals. The treatment with 4 g·L^-1 Fe^2++2 g·L^-1 S0 + bacterial inoculation could achieve the highest metal removal efficiency of 87.3% Cu and 91.9% Zn after 96 h bioleaching. Pig slurry-borne Zn was more easily solubilized than Cu. In addition,the two measured indexes for slurry dewaterability,specific resistance γ and CST of bioleached pig slurry were reduced drastically compared to original pig slurry. Higher Fe^2+ levels produced slurry with better dewaterability. Bioleached pig slurry dewaterability was increased 117 and 205-fold under the treatments of 2 g·L^-1 S0+ 4 g·L^-1 Fe^2+ and 2 g·L^-1 S0+ 5 g·L^-1 Fe^2+,respectively. It was concluded that bioleaching could not only greatly enhance dewaterability of pig slurry,but simultaneously improve the removal of heavy metals. This study might provide a new approach for treatment and disposal of pig slurry.

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期刊信息
  • 《环境科学学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:汤鸿霄
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjkxxb@rcees.ac.cn
  • 电话:010-62941073
  • 国际标准刊号:ISSN:0253-2468
  • 国内统一刊号:ISSN:11-1843/X
  • 邮发代号:82-625
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰地学数据库,荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:56074