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电渗析技术清洁分离纯化肌氨酸
  • ISSN号:0438-1157
  • 期刊名称:《化工学报》
  • 分类:TQ028.8[化学工程]
  • 作者机构:[1]中国科学技术大学化学与材料科学学院,安徽合肥230026, [2]合肥科佳高分子材料科技有限公司,安徽合肥230601
  • 相关基金:国家自然科学基金项目(21276247,21476220)。
中文摘要:

肌氨酸作为一种高附加值的精细化工产品具有广泛的应用前景。目前肌氨酸的生产过程中存在肌氨酸产品与无机盐的分离过程。传统的分离方法为分步结晶法,存在能耗高、消耗的化学试剂多、污染大等缺点。为实现肌氨酸的清洁生产,本文采用自制电渗析装置对肌氨酸进行分离纯化,考察了操作电流以及溶液起始 pH 对整个分离效果的影响。结果表明,当操作电流为2 A,起始pH为6.5时,电渗析过程中无机盐的去除率大于99%,其产品得率为71.5%,电渗析工艺生产肌氨酸的能耗为26.4 kW·h·t-1,总成本仅为311元·t-1,大大优于传统的生产工艺。由此可见,电渗析工艺可实现肌氨酸产品的节能、环保生产。

英文摘要:

Sarcosine is a high-value fine chemical which has many significant applications. Now there is a separation process to remove the inorganic salts from the target product during the production of sarcosine. Multistage fractional crystallization is the conventional separation technology for sarcosine production which has many drawbacks such as high energy consumption, large consumption of chemicals and environmental pollution. To achieve cleaner production of sarcosine, a self-made electrodialysis stack was used in the separation and purification of the target product. The influences of current density and initial pH value in the feed solution on the production of sarcosine were investigated. Results indicated that salt removal rates higher than 99% and a product recovery ratio of 71.5% can be obtained at a current of 2 A and initial feed solution of pH 6.5. The total energy consumption for sarcosine production was 26.4 kW·h·t-1 and the total process cost was estimated at 311¥·t-1, which is much less than the conventional separation technologies. It can be seen that electrodialysis is not only energy-saving but also environment- friendly for the industrial production of sarcosine.

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期刊信息
  • 《化工学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国化工学会 化学工业出版社
  • 主编:李静海
  • 地址:北京市东城区青年湖南街13号
  • 邮编:100011
  • 邮箱:hgxb126@126.com
  • 电话:010-64519485
  • 国际标准刊号:ISSN:0438-1157
  • 国内统一刊号:ISSN:11-1946/TQ
  • 邮发代号:2-370
  • 获奖情况:
  • 中国科协优秀期刊二等奖,化工部科技进步二等奖,北京全优期刊奖,中国期刊方阵“双效”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:35185