我们表明了一个方法制作被用来形成皮克林乳剂(足) 的功能的混合电影补丁。混合补丁用碳 nanotubes 做的, Fe 3 O 4 nanoparticles, octadecyltrimethoxysilane,并且 poly (diallyldimethylammonium 氯化物) 。混合补丁的稳定的足的水的阶段能被使用一个磁场容易分开。hybrid-film-patch 稳定了足为在房间温度的八个月极其稳定、持续。而且,他们被增加乙醇容易破裂,并且在 aqueous/oil 混合物由 vortexing 改革了补丁,启用容易与金属 nanoparticles 要修改的补丁的内部吸水的方面。作为一个例子,钯 nanoparticles 被嵌进混合补丁的表面用一在里面 situ 减小方法。Pd functionalized 补丁形成了显示出的足为有 99.5% 的收益的丙酮的加氢的优秀催化表演。没有催化活动的损失, Pd functionalized 补丁的一样的批被再循环 13 次。混合补丁的形成的足在催化的域里有一个大潜力。
We demonstrated a method to fabricate functional hybrid film patches that were used to form Pickering emulsions (PEs). The hybrid patches were made of carbon nanotubes, Fe3O4 nanoparticles, octadecyltrimethoxysilane, and poly(diallyldimethylammonium chloride). The aqueous phase of the hybridpatch stabilized PEs can be easily separated by applying a magnetic field. The hybrid-film-patch stabilized PEs are extremely stable and lasted for eight months at room temperature. Furthermore, they are easily ruptured by adding ethanol, and regenerated by vortexing the patches in aqueous/oil mixtures, enabling the inner hydrophilic side of the patches to be easily modified with metal nanoparticles. As an example, palladium nanoparticles were embedded into the surface of the hybrid patches using an in situ reduction method. The Pd functionalized patch formed PEs showed an excellent catalytic performance for the hydrogenation of acetone with a yield of 99.5%. The same batch of Pd functionalized patches was recycled 13 times without loss of the catalytic activity. The hybrid-patch formed PEs have a great potential in the catalytic field.