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汽车用聚氨酯减振材料的结构与性能
  • ISSN号:1000-3304
  • 期刊名称:《高分子学报》
  • 时间:0
  • 分类:TN248.01[电子电信—物理电子学]
  • 作者机构:[1]中国科学院长春应用化学研究所高分子物理与化学国家重点实验室,长春130022, [2]中国科学院大学,北京100049, [3]广州中谱检测技术服务有限公司,广州510663, [4]吉林大学材料科学与工程学院教育部汽车材料重点实验室,长春130025
  • 相关基金:国家自然科学基金(基金号21274152,51473168,21234007)资助项目和吉林省科技厅科技发展计划项目(项目号20150301002GX)资助.
中文摘要:

利用扫描电镜(SEM)对减振材料的微孔结构进行了表征;用万能材料试验机(UMTM)、动态热机械分析仪(DMA)、旋转流变仪表征了减振材料在不同条件下的力学及减振性能.研究发现:不同聚氨酯减振材料进入非线性形变区域的压缩形变大小与微孔的面积占有率相关.我们认为聚氨酯泡沫减振材料在小压缩应变下应力的缓慢增加主要是由微孔的变形引起的,随着压缩应变进一步增加,微孔的变形接近极限,此时应力的快速增加主要由聚氨酯本体的力学性能决定.聚氨酯减振材料的损耗能随着压缩应变的增加而增加,减振性能好的材料具有较大的损耗能.聚氨酯减振材料的损耗角随着压缩频率的增加而略有增加,其影响减振材料在不同使用频率下的减振和产热性能.聚氨酯减振材料的损耗角随着温度的变化而发生变化,耐寒性和耐热性好的材料,损耗角随温度平缓变化的温度范围更宽.当减振材料受到一定的负载后,材料的损耗角降低.

英文摘要:

Scanning electron microscope (SEM) was used to study the microcellular structure of the damping material. Universal material testing machine (UMTM), dynamic mechanical thermal analysis (DMA) and rotational rheometer were used to measure the mechanical properties and damping properties under different conditions. For the three different damping materials, it was observed that the value of the critical compression strain where the damping material changed to non-linear deformation regime was connected with the ratio of microcellular area versus the bulk area of cutting surface. It was inferred that the slow growth of stress for damping materials under small compression strain was contributed from the deformation of microcellular. As the compression strain was further increased, the deformation of microcellular reached its limitation, and accordingly, the rapid growth of the stress was mainly caused by the deformation of the bulk polyurethane. It was observed that the hysteresis energy of damping materials increased with the maximum compression strain was increased, and the damping material with better damping properties had bigger hysteresis energy. It was found that the loss angle of damping materials increased slightly with compression frequency, which affects the damping properties and the generated heart of the damping materials with different compression frequency. It was also observed that the loss angle of damping materials changed with temperature, and the loss angle would change slightly under wider range of temperature for the damping material with better low temperature resistance and high temperature resistance. It was also found that the damping properties of samples decreased when a bigger load was applied.

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期刊信息
  • 《高分子学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院化学研究所
  • 主编:张希
  • 地址:北京市海淀区中关村北一街2号
  • 邮编:100190
  • 邮箱:gfzxb@iccas.ac.cn
  • 电话:010-62588927
  • 国际标准刊号:ISSN:1000-3304
  • 国内统一刊号:ISSN:11-1857/O6
  • 邮发代号:2-498
  • 获奖情况:
  • 国家优秀期刊二等奖,中科院优秀期刊二等奖,中国科协优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国高分子图书馆,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:19174