修改氧化铁,为到聚合物电解质燃料房间(PEFC ) 的氢存储和供应的新材料,被与包含金属阳离子添加剂(艾尔, Cr, Ni,公司, Zr 和瞬间) 的一个水的答案使 Fe 或 Fe2O3 粉末妊娠准备。样品的氢存储性质被调查。Fe 和 Fe2O3 与添加剂瞬间搽粉的结果表演介绍了优秀催化活动和周期的稳定性,并且他们生产温度的氢能令人惊讶地被减少。以 250 摩尔的率为 Fe2O3 瞬间形成氢的温度 ???? 愠潺敭桴湩 ?????? ???? 匠档晩 ? 僚 ????
Modified iron oxide, a new material for hydrogen storage and supply to polymer electrolyte fuel cell (PEFC), was prepared by impregnating Fe or Fe2O3 powder with an aqueous solution containing metal cation additives (Al, Cr, Ni, Co, Zr and Mo). Hydrogen storage properties of the samples were investigated. The results show that both Fe and Fe2O3 powder with additive Mo presented excellent catalytic activity and cyclic stability, and their hydrogen producing temperature could be surprisingly decreased. The temperature of forming hydrogen for the Fe2O3-Mo at the rate of 250 μmol·min^-1·Fe-g^-1 could be dramatically decreased from 527 ℃ before addition of Mo to 283 ℃ after addition of Mo in the fourth cycle. The cause for it was probably related to preventing the sinter of the sample particles. In addition, hydrogen storage capacity of the Fe2O3-Mo can reach w=4.5% (72 kg H2/m^3), close to International Energy Agency (IEA) criterion. These show the value of practical application of the Fe2O3-Mo as the promising hydrogen storage material.