位置:成果数据库 > 期刊 > 期刊详情页
一种新型储氢材料——改性四氧化三铁的储氢性能研究
  • ISSN号:0567-7351
  • 期刊名称:《化学学报》
  • 时间:0
  • 分类:TF123.2[冶金工程—粉末冶金;冶金工程—冶金物理化学]
  • 作者机构:[1]Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi'an, Shaanxi 710069, China, [2]State Key Laboratory of Continental Dynamics, Northwest University, Xi'an, Shaanxi 710069, China, [3]Department of Chemistry, Shaanxi Shangluo Normal University, Shangluo, Shaanxi 726000, China
  • 相关基金:Project supported by the National Natural Science Foundation of China (No. 20673082), the Scientific Research Foundation for the Returned 0verseas Chinese Scholars, State Education Ministry (No. 2006331), the Key Project of Science and Technology of Shaanxi Province (No. 2005k07-G2), and the Natural Science Foundation of Shaanxi Education Committee (No. 06JK167).
中文摘要:

修改氧化铁,为到聚合物电解质燃料房间(PEFC ) 的氢存储和供应的新材料,被与包含金属阳离子添加剂(艾尔, Cr, Ni,公司, Zr 和瞬间) 的一个水的答案使 Fe 或 Fe2O3 粉末妊娠准备。样品的氢存储性质被调查。Fe 和 Fe2O3 与添加剂瞬间搽粉的结果表演介绍了优秀催化活动和周期的稳定性,并且他们生产温度的氢能令人惊讶地被减少。以 250 摩尔的率为 Fe2O3 瞬间形成氢的温度 ???? 愠潺敭桴湩 ??????  ???? 匠档晩 ? 僚 ????

英文摘要:

Modified iron oxide, a new material for hydrogen storage and supply to polymer electrolyte fuel cell (PEFC), was prepared by impregnating Fe or Fe2O3 powder with an aqueous solution containing metal cation additives (Al, Cr, Ni, Co, Zr and Mo). Hydrogen storage properties of the samples were investigated. The results show that both Fe and Fe2O3 powder with additive Mo presented excellent catalytic activity and cyclic stability, and their hydrogen producing temperature could be surprisingly decreased. The temperature of forming hydrogen for the Fe2O3-Mo at the rate of 250 μmol·min^-1·Fe-g^-1 could be dramatically decreased from 527 ℃ before addition of Mo to 283 ℃ after addition of Mo in the fourth cycle. The cause for it was probably related to preventing the sinter of the sample particles. In addition, hydrogen storage capacity of the Fe2O3-Mo can reach w=4.5% (72 kg H2/m^3), close to International Energy Agency (IEA) criterion. These show the value of practical application of the Fe2O3-Mo as the promising hydrogen storage material.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《化学学报》
  • 北大核心期刊(2014版)
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院上海有机化学研究所
  • 主编:周其林
  • 地址:上海市零陵路345号
  • 邮编:200032
  • 邮箱:hxxb@sioc.ac.cn
  • 电话:021-54925085
  • 国际标准刊号:ISSN:0567-7351
  • 国内统一刊号:ISSN:31-1320/O6
  • 邮发代号:4-209
  • 获奖情况:
  • 首届国家期刊奖,第二届国家期刊奖提名奖,中国期刊方阵“双高期刊”
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:28694