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助熔剂法生长ZnO晶体
  • ISSN号：1000-985X
  • 期刊名称：《人工晶体学报》
  • 时间：0
  • 分类：O78[理学—晶体学]
  • 作者机构：[1]清华大学化学系,北京100084, [2]人工晶体研究院,北京100018
  • 相关基金：The project supported by the National Natural Scicence Foundation of China（No. 50590402）
作者： 张帆[1], 沈德忠[1,2], 沈光球[1], 王晓青[1]
关键词： 晶体生长, 助熔剂法, 氧化锌, crystal growth, flux method, ZnO
中文摘要：

采用Bi4B2O9、CdB2O4和BaB2O4为助熔剂,获得了毫米级的氧化锌单晶。Mulliken的电负性理论和Viting的平均轨道电负性提供了一个选择晶体生长所采用的助熔剂的有效方法。实验结果表明ZnO晶体的生长温度比文献报道的均低,从而有效地减少了ZnO以及助熔剂的挥发。本文给出了几种有望获得大尺寸ZnO单晶的助熔剂。

英文摘要：

Zinc oxide single crystals with millimeter grade have been grown using Bi4B2O9,CdB2O4 and BaB2O4 as fluxes.The electronegativity theory of Mulliken and the mean orbital electronegativity of Viting provide an effective way to choose the fluxes for crystal growth.The crystal growth temperature is relative lower than that of the reported literatures,decreasing the volatilization of ZnO and the fluxes effectively.It provides new promising fluxes to grow large-sized ZnO single crystal.

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期刊信息
  • 《人工晶体学报》
  • 中国科技核心期刊
  • 主管单位:中国建材工业协会
  • 主办单位:中国硅酸盐学会 晶体生长与材料专业委员会 中材人工晶体研究院
  • 主编：余明清
  • 地址：北京市733信箱
  • 邮编：100018
  • 邮箱：
  • 电话：010-65492963 65492968 65493320
  • 国际标准刊号：ISSN：1000-985X
  • 国内统一刊号：ISSN：11-2637/O7
  • 邮发代号:
  • 获奖情况:
  • 1997年获国家科技优秀期刊,获部级优秀科技期刊奖,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,中国北大核心期刊（2000版）
  • 被引量:9943