高储能密度聚合物基复合电介质材料在电容器领域具有很高的应用价值,目前很多研究集中在本身具有较高的介电常数的铁电材料上。通过探讨铁电聚合物基纳米复合电介质材料储能理论、电极化特性、充放电效率等与储能密度密切相关的性能,深入分析了复合电介质材料的储能机理并提出了下一步的发展方向。并进一步讨论了目前铁电聚合物基复合电介质材料的主要制备策略,包括纳米填料表面修饰改性、多相共混复合和多层结构调控以及由此实现的介电性能和储能密度的提升。
Polymer-based composite dielectric materials with high energy density have potential application in the ca- pacitor field, and many researches focus on ferroelectric materials due to their high permittivity. We discussed the energy storage theory, electric polarization characteristics, charge-discharge efficiency of ferroelectric polymer-based nanocom- posite dielectrics that are closely related with energy density, analyzed the energy storage mechanism, and proposed the development prospection. Moreover, we further investigated the main fabrication strategies including surface modifica- tions of nanofillers, ferroelectric polymer-based composites of multi-phase blends, managements of multi-layer structure, the resultant promoted dielectric properties, as well as high energy density.