采用超临界CO2、H2O和表面活性剂聚乙二醇三甲基壬基醚(TMN-6)构建了水包C02的乳液体系,探索了CO2/水乳液体系的形成条件,利用高压落球黏度计测试了CO2/水乳液体系的黏度,考察了TMN-6质量浓度、体系温度、CO2压力及mH2O:mCO2对乳液体系黏度的影响。实验结果表明,在25~40℃,10~25MPa,mCO2:mH2O=(2:8)~(5:5),TMN-6质量浓度在0.2%~1.5%条件下,可形成稳定的CO2/水乳液体系;乳液体系的黏度随TMN-6质量浓度的增加、CO2压力的升高、温度的降低及mH2O:mCO2的增加有不同程度的增大,且随着TMN-6质量浓度的增加,CO2/水乳液体系黏度与温度和压力的相关性也逐渐增加。
CO2/water emulsion could be formed using supercritical CO2, H2O and surfactant poly (ethylene glycol) 2, 6, 8-trimethyl-4-nonyl ether(TMN-6). The formation conditions for CO2/water emulsion were investigated. The viscosity of the CO2/water emulsion was measured using the high pressure falling ball viscometer. The effects of the surfactant concentration, temperature, CO2 pressure and mH2O :mCO2 on the emulsion viscosity were studied. The results showed that the viscosity of the emulsion was much higher than that of CO2 or water. At 25-40 ℃, CO2 pressure of 10-25 MPa, mH2O : mCO2 between (2 : 8)- (5 : 5), and TMN-6 concentration(w) of 0.2%-1.5%, the viscosity of CO2/water emulsion increased with increasing the TMN-6 concentration, CO2 pressure and mH2O : mCO2, and decreasing the temperature. In addition, it was showed that the dependence of the CO2/water emulsion viscosity on temperature and pressure were gradually enhanced with increasing surfactant concentration.