采用自悬浮定向流法制备的纳米Cu粉末具有一定的粒径分布范围,获得分布更窄、更均一的纳米粉末具有重要的应用价值,以达到更加突出的物理性质。本文通过测定纳米Cu-水悬浮液的Zeta电位和吸光度,探讨了不同pH值下以及不同浓度下的十二烷基磺酸钠(SDS)对纳米Cu粉末在水中分散性的影响。结果表明:Zeta绝对值越大,分散稳定性越好。在0.01%纳米Cu-水悬浮液中,在pH值为8.5,SDS分散剂加入量为0.024%(质量)时,分散性最好。在此条件下观察沉降颗粒,在4~8 h时间段内得到的沉降颗粒平均粒径为62 nm单分散性较好的颗粒,且为主要产物。
The nano-Cu powder are in a certain range of particle size distribution prepared by flow-levitation technology.The exploration is aim at making the distribution of the powder more narrow and more uniform,in order to achieve a more prominent physical properties.Dispersion and stability of nano-Cu particles in water were studied under different pH values and dispersant concentration by the method of Zeta potential and absorbency.The results show that: the higher Zeta potential is,the better dispersion and stability of nano-Cu/water suspension are.When the dispersion and stability of 0.01% nano-Cu/water suspension is the best,pH 8.5 can be selected as an operating pH,and the 0.024% SDS can be selected as an optimizing concentration.Observing the sedimentation particles under these conditions,the average particle size is about 62 nm from 4 to 8 h period of time and as the main product.