中文摘要：

以合成的1，3，5-三（p-羟基苯基）苯（TP）、烯丙基胺和甲醛为原料，合成了一种新型的含烯丙基的三元酚型苯并噁嗪单体——1，3，5-三（3-烯丙基-3，4-二氢-2H-1，3-苯并噁嗪基）苯（tp-ala）．采用核磁共振谱、傅里叶变换红外光谱、紫外-可见吸收光谱和差示扫描量热表征了tp-ala的结构和固化行为，用热失重分析、动态热机械分析和荧光光谱测试了固化物P-tp-ala的热性能及光学性能．结果表明，烯丙基的引入使P-tp-ala玻璃化转变温度高达322℃，5％的热失重温度为351℃，800℃残炭率达到61．4％，与不含烯丙基的三元酚型苯并噁嗪相比具有较好的耐热性．在233nm激发波长下，P-tp-ala的荧光发射波长为350nm，具有荧光性能．由于P-tp—ala中的芳香含量高，使其折射率高达1．6325，在防折射涂层方面有很好的应用潜力．

英文摘要：

1,3,5-Tri （ 3-allyl-3,4-dihydro-2H- 1,3-benzoxa-zinyl ） benzene （tp-ala） was synthesized using allyl amine, para-formaldehyde and new synthesized 1,3,5-tri （p-hydroxyl-phenyl）benzene. The chemical structure of tp-ala was characterized by nuclear magnetic resonance spectroscopy （^1H NMR, ^13C NMR）, Fourier trans- form infrared spectroscopy （FTIR） and ultraviolet and visible absorption spectroscopy （UV-Vis）. The curing behavior of tp-ala was studied by differential scanning calorimetry （DSC） analysis. The thermal and optical properties of cured tp-ala（P-tp-ala） were observed. The results showed that by introducing the allyl-group, the Tg of P-tp-ala was 322 ℃. 5% mass loss temperature was at 356 ℃ and the char yield at 800 ℃ was 61.4%, which were higher than those of the reported trisphenol-based polybenzoxazines. P-tp-ala also showed photolumineseent property. The fluorescence emission wavelength of P-tp-ala under an excitation at 233 nm was at 350 nm. In addition, due to the high aromatic content of P-tp-ala, P-tp-ala had a high refractive index of 1. 6325. The high refractive-index characteristic makes P-tp-ala thermoset a potential candidate in antireflective coating.