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两个由1，1′-环己烷二乙酸构筑的镉的配合物的合成、晶体结构和荧光性质
  • ISSN号：1001-4861
  • 期刊名称：《无机化学学报》
  • 时间：0
  • 分类：O614.242[理学—无机化学;理学—化学]
  • 作者机构：[1]中科院福建物质结构研究所、结构化学国家重点实验室,福州350002, [2]中科院研究生院,北京100049
  • 相关基金：国家自然科学基金（No.90206040,20325106,20333070）、福建省自然科学基金（No.E0520003）和中科院“百人计划”项目基金资助.
作者： 何锦润[1,2], 王玉玲[1,2], 毕文华[1,2], 曹荣
关键词： 柔性配体, 镉配合物, 1, 1′一环己烷二乙酸, 溶剂热合成, 荧光, flexible ligand, Cd（Ⅱ） complex, 1,1′-cyclohexanediacetic acid, solvothermal synthesis, fluorescence
中文摘要：

通过邻羧苯乙酸，1，10-邻菲哕啉及硝酸镉的溶剂热反应合成了2个配合物：[Cd（phen）（chdc）]n（1）和[Cd（phen）（chdc）（H2O）]n（2）。X-射线单晶衍射显示：1是梯状双链结构；2是单链结构，单链再通过氢键连接成双链。虽然1和2的组分相似，但它们在固态条件下的荧光发射却大不一样，可能在光化学方面有潜在的应用。

英文摘要：

Two complexes of 1,1′-cyclohexanediacetic acid （H2chdc）, [Cd（phen）（chdc）]n （1） and [Cd（phen）（chdc） （H2O）]n （2）, have been synthesized through solvothermal reactions of H2chdcc, 1,10-phenanthroline （phen） and cadmium nitrate. The crystal structures of two complexes reveal that 1 has a ladder-like double-chain structure, while 2 consists of linear single chains, which are further linked to form double-chains through hydrogen bonding. Although consisted of similar components, 1 and 2 exhibit different intense fluorescence emission in solid state, which may have promising application in photophysical chemistry. CCDC： 285079, 1; 285080, 2.

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期刊信息
  • 《无机化学学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国化学会
  • 主编：游效曾
  • 地址：南京市南京大学仙林区化学楼
  • 邮编：210023
  • 邮箱：wjhx@nju.edu.cn
  • 电话：025-89682307
  • 国际标准刊号：ISSN：1001-4861
  • 国内统一刊号：ISSN：32-1185/O6
  • 邮发代号:28-133
  • 获奖情况:
  • 2007年获江苏省优秀期刊奖,2009年获华东地区优秀期刊奖
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:19587