以不同交联度、溶胀程度的双亲无规共聚物聚[(苯乙烯-alt-马来酸酐)-co-(7-对乙烯基苄氧基-4-甲基香豆素-alt-马来酸酐)](PSMVM)胶束作为聚合物胶束乳化剂稳定甲苯,水体系,重点研究光交联度对胶束结构及其乳化性能的影响.结果表明,胶束交联度、溶胀度和荷电性对胶束结构及乳化性能有较大影响.
The photosensitive amphiphilic copolymer poly-(styrene-alt-maleic anhydride)-co-poly (7-(4- vinylbenzyloxyl)-4-methylcoumarin-alt-maleic anhydride) (PSMVM) micelles with various degrees of swelling were used as polymeric micellar emulsifiers to stabilize toluene-in-water emulsions. This paper focuses on the influence of the degree of photo-crosslinking on the micellar structure and the emulsification performance of the micelles. The research results indicated that the degree of photo-crosslinking, the degree of swelling, and the charge on the micelles played an important role in the micellar structure and the emulsifying performance of the micelles.