中文摘要：

以二氰基二硫纶（mnt）和4,7-二苯基-1,10-菲咯啉为配体,混配得到Mn2＋、Fe2＋、Co2＋配合物,通过其在丙酮（Acet）、二甲基亚砜（DMSO）和氯仿（CHCl3）中的电子吸收光谱,得出了电子光谱吸收带在相关分子轨道能级图中的对应跃迁关系,并对其在二甲基亚砜中的光致氧化特性进行了实验研究.

英文摘要：

Complexes M（mnt）（4,7-diphenyl-1,10-phene） were synthesized by dicyano-1,2-ethylenedithiolate and 4,7-diphenyl-1,10-phenanthroline.The electronic absorption spectra of complexes M（mnt）（4,7-diphenyl-1,10-phene）（M=Mn（Ⅱ）,Fe（Ⅱ）,Co（Ⅱ）;mnt= 1,2-dicyano-1,2-ethylenedithiolate;4,7-diphenyl-1,10-phene= 4,7-diphenyl-1,10-phenanthroline） in dimethyl sulfoxide（DMSO）,acet and CHCl3 were studied.The relation between electronic spectra absorption band and correlative transition in the molecular orbital energy level diagram of complex was investigated.The photo-oxydation characteristics of the synthesized complexes in DMSO was tested.