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氟乐灵微囊的制备、表征及其光稳定性研究
  • ISSN号:1008-7303
  • 期刊名称:《农药学学报》
  • 时间:0
  • 分类:TQ450.68[化学工程—农药化工]
  • 作者机构:[1]农业部作物有害生物综合治理重点实验室、中国农业科学院植物保护研究所,北京100193, [2]甘肃农业大学草业学院,兰州730070
  • 相关基金:国家自然科学基金资助项目(31471805;31301701)
中文摘要:

为增强氟乐灵的光稳定性,提高其有效利用率,以壳聚糖(CS)和甲基丙烯酸甲酯(MMA)为壁材,采用原位聚合法制备了氟乐灵微囊,并测定了其外观形态、粒径及其分布、包封率和载药量,同时研究了其释放特性及其在土壤和水中的光稳定性。结果表明:所制备的氟乐灵微囊呈规则球形;粒径在3~10μm之间,平均粒径为6.5μm;包封率和载药量分别为79%和45%;该微囊具有良好的缓释性能,释放以Fick扩散为主;与氟乐灵乳油相比,氟乐灵微囊的光稳定性显著增强,在试验条件下,其在土壤表面和水中的光解半衰期分别为22 d和173 min。

英文摘要:

Trifluralin-loaded microcapsules were prepared by in situ polymerization using chitosan and methyl methacrylate as carder materials in order to enhance its photo-stability and effective utilization. The surface morphology, size and size distribution, encapsulation efficiency and loading content of the resulting microcapsules were determined. The release characteristics and the photo-stability in soil and water of the microcapsules were studied. The trifluralin-loaded microcapsules dispersed as individual particles with a well-defined spherical shape with average size 6. 5 μm. Most of the microcapsules were between 3 and 10 μm. The encapsulation efficiency and loading content of the microcapsules were 79% and 45%, respectively. The trifluralin-loaded microcapsules had a good sustained release performance and the release was controlled mainly by Fick diffusion. Compared with trifluralin emulsifiable concentrate, photo-stability of the microcapsules was enhanced with the half-lives 22 d in soil and 173 min in water under the experimental conditions.

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期刊信息
  • 《农药学学报》
  • 北大核心期刊(2011版)
  • 主管单位:国家教育部
  • 主办单位:中国农业大学
  • 主编:王道全
  • 地址:北京市海淀区圆明园西路2号中国农业大学理学院
  • 邮编:100193
  • 邮箱:nyxuebao@263.net
  • 电话:010-62733003
  • 国际标准刊号:ISSN:1008-7303
  • 国内统一刊号:ISSN:11-3995/S
  • 邮发代号:2-949
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),波兰哥白尼索引,美国剑桥科学文摘,英国动物学记录,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:8245