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中文摘要：
本项目根据原定计划，充分发挥超分子作用和识别原理，着眼于晶体工程原理，以配合物为基块合成和组装多维手性空间聚合物。以高新技术中的光电功能为主导，开展手性配位聚合物的基础研究。顺利完成了原定目标，在手性配位聚合物的组装、手性磁性配合物和手性磁体、手性铁电及多铁性配合物等方面取得了一系列重要进展。如利用双四唑配体与ZnCl2反应得到具有沸石型孔洞结构的配位聚合物；利用手性配体控制化合物晶体的极性空间群得到一个目前最简单的分子基铁电体，并用气相沉积法制备了第一个分子基铁电薄膜；开展了同时具有铁电和磁性（多铁性）的金属-有机杂化多功能体系的研究，得到了具有磁各向异性的多铁性金属有机簇合物和具有单链磁体行为的多铁性金属有机簇合物等。本项目的基础研究部分已在SCI杂志上发表论文106篇，其中影响因子大于3的重要刊物有58篇。申请专利16项。2009年，南京大学分别举办了“第二届亚洲配位化学会议”和“第十三届亚洲化学会议之无机和纳米分会”（游效曾为上述两个会议主席）。项目组负责人共做各种会议报告28次，其中国际特邀报告10次。
结论摘要：
英文主题词Coordination polymers; Chiral solids; Chiral magnets; Ferroelectrics；Structure and Property
成果综合统计
期刊论文
会议论文
专利
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著作
期刊论文
A New Crown Ether Annelated Tetrathiafulvalene Derivative with Anthracene moiety as a Sensor for Li+
Two-dimensional cyanide-bridged heterobimetallic complexes based on CpCo(CN)3-: syntheses, structure
Fluorescent probe for Na+: synthesis and spectroscopic studies of exocyclic ring-fused boron dipyrro
Syntheses, Structures and Magnetic Properties of Cyano-Bridged Dinuclear Complexes Based on [(Tp)Fe(
Syntheses, Structures and Magnetic Properties of Cyano-Bridged Heterobimetallic Complexes Based on [
Cyano-Bridged Pentanuclear FeIII3MII2 (M = Ni, Co, Fe) Clusters: Synthesis, Structures, and Magnetic
Synthesis, crystal structure and luminescent property of the novel m-thiocyanato-bis[(2-acetylpyridi
Novel Heterometallic 3d-4f Metal-Azido Complex of Mixed Ligands with Unprecedented Structure Type: S
Silver(I) Complexes in Coordination Supramolecular System with Bulky Acridine-Based Ligands: Synthes
Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged Heterobimetallic Chains Base
Mono- and di-(dimethylamino)styryl substituted boron-dipyrromethene (BDP) and boron- diindomethene (
An azido–metal–isonicotinate complex showing long-range ordered ferromagnetic interaction: synthesis
3D MnII coordination polymer with alternating azide/azide/formate/formate bridged chains: synthesis,
Zinc and Cadmium Coordination Polymers with Bis(tetrazole) Ligands Bearing Flexible Spacers: Synthes
Varying Ligand Backbones for Modulating the Interpenetration of Coordination Polymers Based on Homol
Self-assembly of Metal-Organic Coordination Polymers Constructed from a Versatile Multi-pyridyl Liga
Metal?Organic Coordination Polymers Generated from Chiral Camphoric acid and Flexible Ligands with D
Metal–organic coordination architectures of azole heterocycle ligands bearing acetic acid groups: Sy
Tuning the formation of copper(I) coordination architectures with quinoxaline-based N,S-donor ligand
Synthesis and Characterization of New Ruthenium(II) Complexes Containing Coupled Di(2-pyridyl) and 1
Transition metal complexes based on pyridine ligand containing both bis(2-pyridyl) and 1,3-dithiole-
Zinc(II) and mercury(II) coordination architectures with two pyridyl/benzimidazol-1-yl-based ligands
Silver(I) complexes with a bulky acridine-based carboxylic ligand: Syntheses, crystal structures, an
A single-helix copper-containing coordination polymer of dihydroglyoxaline sulfide formed in situ th
Syntheses, Structure, Magnetic Properties and Fe-57 Mossbauer Spectroscopies of Two Iron(II) Complex
Angular Dipyridyl Ligands 2,5-Bis(4-pyridyl)-1,3,4-oxadiazole and Its 3-Pyridyl Analogue as Building
Assembling Chirality into Magnetic Nanowires: Cyano-Bridged Iron(III)-Nickel(II) Chains Exhibiting S
Interconversion of two new nickel(II) coordination polymers with different topologies: synthesis, st
Tuning the Framework Topologies of CoII-Doped ZnII-Tetrazole-benzoate Coordination Polymers by Ligan
An Unusual 1D Manganese Azido Complex with Novel EO/EO/EO/EE Coordination Mode: Synthesis, Structure
Metal Coordination Architectures of 1,4-Bis(imidazol-1-ylmethyl)naphthalene: Syntheses, Crystal Stru
Arenedisulfonate–lanthanide supramolecular architectures with phenanthroline as a co-ligand: synthes
New d10 metal–organic coordination polymers with 9,10-bis(triazol-1-ylmethyl)anthracene (L): Synthes
One-dimensional azido-bridged chiral copper(II) coordination polymers: syntheses, structures and mag
Spin-crossover iron(II) complexes [Fe(Medpq)(py)2(NCS)?2] and [Fe(Medpq)(py)2(NCSe)2]: syntheses, ch
Synthesis, Crystal Structures and Spectroscopic Properties of Two Difluoroboradiaza-s-indacene (BDP)
Tuning the silver(I) complexes of 3-(2-pyridyl)pyrazole-based ligands: Syntheses and crystal structu
Synthesis, crystal structures, and magnetic properties of two cyano-bridged heterobimetallic complex
Molecule-Based Ferroelectric Thin Films: Mononuclear Lanthanide Enantiomers Displaying Room-Temperat
Magnetic canting or not? Two isomorphous 3D CoII and NiII coordination polymers with the rare non-in
Syntheses, Structures, and Electrochemical Properties of Platinum(II) Complexes Containing Di- tert-
Crystal Structures, Magnetic and Ferroelectric Properties of Chiral Layered Metal-Organic Frameworks
Synthesis and Magnetic Properties of a Highly Conducting Neutral Nickel Complex with Highly Conjugat
Two New Copper Azido Polymorphs: Structures, Magnetic Properties, and Effects of “Noninnocent” Reage
Metal–organic coordination architectures of 9,10-bis(N-benzimidazolyl)anthracene: syntheses, structu
Syntheses, Structures and Properties of Tricarbonyl Rhenium(I) Heteronuclear Complexes with New Brid
Rhenium(I) Tricarbonyl Complexes with New Pyridine Ligands Containing Crown Ether Annelated or Anthr
Silver(I) coordination architectures with quinoxaline-based N,S-donor ligands: structures and lumine
Coordination architectures of 2-(1H-tetrazol-5-yl)pyrazine with group IIB metal ions: luminescence a
Zinc(II) coordination architectures with two bulky anthracene-based carboxylic ligands: crystal stru
Structural Diversity and Modulation of Coordination Architectures with Flexible Dithioether or Disul
A photoluminescent 3D silver(I) coordination polymer with mixed ligands anthracene-9,10-dicarboxylat
New fluorescent benzocrown ether derivatives of tetrathiafulvalene: facile synthesis and recognition
Two new Cu(II) complexes with 3-(2-pyridyl)pyrazol-based ligands: Synthesis, crystal structures, and
Hydrothermal Synthesis, Crystal Structures and Luminescent Properties of Two Lanthanide (III) Comple
An azido–CuII–triazolate complex with utp-type topological network, showing spin-canted antiferromag
Syntheses, Electrochemical studies and Crystal Structures of New Unsymmetrical Tetrathiafulvalene Ca
“Nickel(II)–azido ferromagnetic chains in a 3D porous metal–organic framework with breathing guest m
Tuning silver(I) coordination architectures by ligands design: from dinuclear, trinuclear, to 1D and
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