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中文摘要：
设计并合成多种维数不同的聚合金属配合物；研究了组装条件、模板分子、反离子等对聚合金属配合物的空间排列及维数的影响；研究了这些化合物的非线性、发光、磁性等、气体吸附等方面的性质与功能。探讨空间结构与性质和性能之间的关系规律，建立了混合有机配体与金属离子自组装成结构新颖的配位聚合物和一些定向组装配位聚合物的新方法。在结构上证明Gillard机理，并提出利用水热法进行不称有机反应的方法。本成果为进一步实现配位聚合物的定向组装与功能化提供了重要的理论和实验基础。
英文摘要：
Coordination Polymers ,Molecular Assembly ,Supramolecular Chemistry
结论摘要：
本课题主要研究欧氏空间或仿射空间中曲面或子流形的各种变形理论,对于欧氏空间中曲面的各种等矩变形目前已探到不少结果,在国内外数学杂志上这三年来共发表论文六篇,有的论文曾在国内或国外学术会议上进行过交流,已经正式发表的论文都在美国数学评论杂志上作过评论,还有国内外同行来信索要我的论文资料有的发示愿意与我进行合作研究.美国同行IM,Roussos表示愿意作为一个仿问学者来武大共同合人研究变形的课题,目前课题虽然已基本上完成,但还有许多问题有持进一步深入研究,特别是在仿射空间中的许多课题运须继续探讨,在我们这个课题组中的年轻人全部出国深造至今未归,因此深感后继无人,这是目前存在的问题.
成果综合统计
期刊论文
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期刊论文
Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{C
Four two-dimensional highly undulat- ing silver(I)-hexamethylenetetramine coordination networks cont
Syntheses, structures and properties of three novel coordination polymers of silver(I) aromatic dica
Syntheses and crystal structures of four metal-organic coordination networks constructed form cadmiu
Synthesis, structures and second harmonic effect of bis(m2-3,5-dinitrobenzoato- O,O')zinc(II) and te
Hydrothermal synthesis and crystal structures of [M(tp)(4,4'-bipy)] (M = Co(II), Cd(II) and Zn(II)):
Syntheses and crystal structures of five two-dimensional networks constructed from staircase-like si
Organic-inorganic hybrid materials assembled through weak intermolecular interactions. Synthesis, st
The first noncluster vanadium(IV) coordination polymers: Solvothermal syntheses, crystal structure a
Influence of ligand backbones and counter ions on structures of helical silver(I) complexes with di-
Systematic study of synthesis and crystal structures of Ag(DPK)nX complexes (DPK = di-2-pyridyl keto
Two new octadecanuclear copper(II)-lanthanide(III) clusters encapsulating m9-NO3- anions. Synthesis,
Synthesis, crystal structures and magnetic properties of monomeric and imidazolate- bridged polymeri
A three-dimensional honeycomb-like network constructed with novel one-dimensional S-shaped chains vi
Cocrystallization of hexamethylenetetramine (hmt) with dicarboxylic acids. Crystal structures of fou
An octanuclear copper(II) complex self-assembled with divalent gem-diol form anion of di-2-pyridyl k
Synthesis, crystal structure and physical properties of two terephthalate-bridged copper(II) and nic
A novel polycatenated double-layered hybrid organic-inorganic material con- structed from [Zn2(tp)(4
Molecular ladders with multiple interpenetration of the lateral arms into the squares of adjacent la
Synthesis and structure of a photo-luminescent three-dimensional network [AgL(MeCN)] (L = 4,5-dichlo
catena-Poly[[[bis(O-perchlorato)(1,10-phenanthroline-N,N')copper(II)](m2-4,4'-bipyridine-N:N')] mono
Synthesis, crystal structure and e.p.r. spectra of one-dimensional manganese(II) 3,5-dinitrobenzoate
Synthesis and structures of two-dimensional coordination polymers constructed by metal salts and 4,4
A blue photoluminescent three- dimensional coordination polymer constructed with helical [Zn3(μ3- OH
Syntheses and structures of three two-dimensional silver(I)-hexamethyl- enetetramine coordination po
Syntheses and structures of six chain-, ladder- and grid-like coordination poly- mers constructed fr
Synthesis and structures of dichlorotetrakis(phenylthiourea)cadmium(II) and catena- bis(thiocyanate)
Crystal structure of tetrakis(3,5-dinitrobenzoato)cadmium di(aquasodium) hemihydrate hemi(3,5-dinitr
Three-dimensional structure constructed via hydrogen bonds and p-p stacking interaction. Crystal str
Self-assembly of two- and three-di- mensional coordination networks with hexamethylene- tetramine an
Toward designed assembly of microporous coordination networks constructed from the silver(I)- hexame
Ferrimagnetic-like ordering in a unique three-dimensional coordination poly- mer featuring mixed azi
Self-assembly of new 3D molecular architectures constructed from silver(I)- hexamethylenetetramine l
Synthesis, crystal structures and magnetic properties of two methoxo-bridged dimeric copper(II) comp
Coordination networks self-assembled by transition metal salts with 4,4￠-oxydianiline (4,4￠-oda). Sy
Crystal structures of two- and three-dimensional polymeric complexes assembled by metal pseudohalide
Syntheses, crystal structures and phy- sical properties of dinuclear copper(I) and tetranuclear mixe
Synthesis, structures and photolumine- scence of three terbium(III) dicarboxylate coordination polym
Interlocking of molecular rhombi into 2D polyrotaxane network via p-p interactions. Crystal structur
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