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基于智能纳米孔道的仿生能量转换与存储从机理到原型器件
  • 项目名称：基于智能纳米孔道的仿生能量转换与存储从机理到原型器件
  • 项目类别：重大研究计划
  • 批准号：91127025
  • 申请代码：B010702
  • 项目来源：国家自然科学基金
  • 研究期限：2012-01-01-2015-12-31
  • 项目负责人：江雷
  • 负责人职称：研究员
  • 依托单位：中国科学院化学研究所
  • 批准年度：2011
中文摘要：

能源是人类社会赖以生存和可持续发展的基础，寻找更为高效环保的能源转换与存储材料成为全人类都必须面对的最大挑战之一。自然界中的生命体系通过40多亿年的进化，实现了对能源的高效利用，特别是生物膜离子通道在其中起着重要作用。本项目将生命体系中高效能量转换与存储的基本原理用于仿生能源材料的设计和制备，通过功能分子设计，以及在固体纳米孔道界面的可控自组装过程，制备仿生纳米通道单元；研究智能孔道内能量转换与储存的机理；研究纳米孔道内多层次、多组份的可控自组装过程及其对材料性能的调控；并最终将智能孔道单元集成为智能薄膜材料和原型器件。重点研究模仿电鳗放电的新型能差纳流电池，模仿视觉原理的质子光电转换器件，仿生非对称膜结构，外场调控下的孔道内分子自组装过程与组装体结构，以及智能孔道单元的多尺度集成。由此获得一批具有自主知识产权的仿生产能及储能材料与器件，为仿生能源领域的发展提供新知识、新方法和新材料。

中文主题词： 仿生体系；纳米通道；复合材料；多尺度；非对称
英文摘要：

bio-inspired system；nanopores；composite materials；multiscale；asymmetry

英文主题词： bio-inspired system；nanopores；composite materials；multiscale；asymmetry
结论摘要：

我们将功能分子的刺激-响应特性拓展到固体纳米孔道中，构筑了一系列具有类生物膜离子通道开关和整流特性的智能纳米孔道。通过模仿电鳗起电盘隔膜的结构和发电原理，首次提出利用仿生纳米孔道进行盐差能转换的机理和原型器件，提出了纳流体反向电渗析的概念，从实验和理论上完成了基于单通道的基础研究工作。本项目立足仿生能源材料这一主题，合成与制备仿生智能孔道隔膜材料，构筑宏观产能器件，并结合理论模型，研究纳米孔道膜结构中与能量转换相关的基本规律。

成果综合统计
成果类型
数量
  • 期刊论文
  • 会议论文
  • 专利
  • 获奖
  • 著作
  • 112
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期刊论文
The art of aligning one-dimensional (1D) nanostructures
Fabricating Surfaces with Tunable Wettability and Adhesion by Ionic Liquids in a Wide Range
Directional Drop Transport Achieved on High-Temperature Anisotropic Wetting Surfaces
Directional Motion and Adhesion of Tiny Droplets on Bioinspired Spindle-Knotted TiO2 Fibers
Bioinspired Conical Copper Wire with Gradient Wettability for Continuous and Efficient Fog Collectio
"Liquid-Liquid-Solid"-Type Superoleophobic Surfaces to Pattern Polymeric Semiconductors to
A bio-inspired flexible fiber array with an open radial geometry for highly efficient liquid transfe
Design of bioinspired, smart, multiscale interfacial materials with superwettability
Spear and Shield: Survival War between Mantis Shrimps and Abalones
A Bio-inspired Potassium and pH Responsive Double-gated Nanochannel
Applications of polymer single nanochannels in biosensors
Bioinspired Gas Bubble Spontaneous and Directional Transportation Effects in an Aqueous Medium
Chinese brushes: From controllable liquid manipulation to template-free printing microlines
Superwettability Controlled Overflow
Directly Coating Hydrogel on Filter Paper for Effective Oil-Water Separation in Highly Acidic, Alkal
Ion Transport in DNA Superstructure Modified Diamond-shaped Nanopores
In Situ Wetting State Transition on Micro- and Nanostructured Surfaces at High Temperature
Photoelectric cooperative patterning of liquid permeation on the micro/nano hierarchically structure
Bio-Inspired Multistructured Conical Copper Wires for Highly Efficient Liquid Manipulation
Bio-Inspired Titanium Dioxide Materials with Special Wettability and Their Applications
Malachite Green Derivative-Functionalized Single Nanochannel: Light-and-pH Dual-Driven Ionic Gating
A Biomimetic Multi-Stimuli-Response Ionic Gate Usinga Hydroxypyrene Derivation-Functionalized Asymme
High-Performance Ionic Diode Membrane for Salinity Gradient Power Generation
A bio-inspired sensitive and selective ionic gate driven by silver (I) ions
Filefish-Inspired Surface Design for Anisotropic Underwater Oleophobicity
Manipulating and Dispensing Micro/Nanoliter Droplets by Superhydrophobic Needle Nozzles
Phototunable Underwater Oil Adhesion of Micro/Nanoscale Hierarchical-Structured ZnO Mesh Films with
Inkjet Printing Patterned Photonic Crystal Domes for Wide Viewing-Angle Displays by Controlling the
Rapid Generation of Cell Gradients by Utilizing Solely Nanotopographic Interactions on a Bio-Inert G
Patterning of controllable surface wettability for printing techniques
Chinese Brushes: Controllable Liquid Transfer in Ratchet Conical Hairs
Temperature-driven switching of water adhesion on organogel surface
Patterned liquid permeation through the TiO2 nanotube array coated Ti mesh by photoelectric cooperat
Bio-inspired Smart Single Asymmetric Hourglass Nanochannels for Continuous Shape and Ion Transport C
Underwater Self-Cleaning Scaly Fabric Membrane for Oily Water Separation
Electrospun Porous Structure Fibrous Film with High Oil Adsorption Capacity
Synthetic Asymmetric-Shaped Nanodevices with Symmetric pH-Gating Characteristics
Direct Insight into the Three-Dimensional Internal Morphology of Solid-Liquid-Vapor Interfaces at Mi
Building Bio-Inspired Artificial Functional Nanochannels: From Symmetric to Asymmetric Modification
A Fluoride-Driven Ionic Gate Based on a 4-Aminophenylboronic Acid-Functionalized Asymmetric Single N
Cactus Stem Inspired Cone‐Arrayed Surfaces for Efficient Fog Collection
Mechanical exfoliation of track-etched two-dimensional layered materials for the fabrication of ultr
Bioinspired One-Dimensional Materials for Directional Liquid Transport
Target-Specific 3D DNA Gatekeepers for Biomimetic Nanopores
Ionic-Liquid-Gel Surfaces Showing Easy-Sliding and Ultradurable Features
Manipulating Overflow Separation Directions by Wettability Boundary Positions
Concentration-Gradient-Dependent Ion Current Rectification in Charged Conical Nanopores
Elaborately Aligning Bead-Shaped Nanowire Arrays Generated by a Superhydrophobic Micropillar Guiding
Elaborate Positioning of Nanowire Arrays Contributed by Highly Adhesive Superhydrophobic Pillar-Stru
Terminating Marine Methane Bubbles by Superhydrophobic Sponges
Highly-E？cient Gating of Solid-State Nanochannels by DNA Supersandwich Structure Containing ATP Apta
Engineered Asymmetric Heterogeneous Membrane: A Concentration-Gradient-Driven Energy Harvesting Devi
Chiral recognition of L-tryptophan with beta-cyclodextrin-modified biomimetic single nanochannel
Ultratrace detection of glucose with enzyme-functionalized single nanochannels
Large-Scale Assembly of Organic Highly Crystalline Multicomponent Wires through Surface-Engineered C
Underwater Thermoresponsive Surface with Switchable Oil-Wettability between Superoleophobicity and S
A multi-structural and multi-functional integrated fog collection system in cactus
Nanopore-based sensing and analysis: beyond the resistive-pulse method
平行四面体纳米孔道中DNA超结构的组装和离子输运特性
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