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中文摘要：
根据当前国际上阴离子识别受体的研究进展情况, 针对质子化溶剂（水或乙醇等）亦能与阴离子形成氢键与受体识别位点竞争结合阴离子的状况，为开发能在实际中应用的新颖的阴离子传感器进行探索研究，以及在与阴离子结合过程中阴离子诱导识别受体产生异构变化将有助于开发新型生物阴离子荧光传感器,并结合国家自然科学基金项目（20671052）设计、合成了50多个新颖的阴离子识别主体，利用1HNMR、元素分析、质谱对所合成识别受体进行表征。并利用Uv-Vis光谱滴定和荧光光谱滴定测定了所合成的阴离子识别受体对CMP、CDP、CTP、dCMP、dTMP、AMP、ADP、AMP等核苷酸阴离子以及AcOˉ、H2PO4ˉ、OHˉ、Fˉ、Clˉ、Brˉ、Iˉ等重要阴离子在DMSO溶液和DMSO/H2O混合溶液中的的结合常数。利用1HNMR滴定和X-射线衍射（晶体结构测定）以及量子化学计算研究了所合成的阴离子识别受体对阴离子进行识别的机理研究。利用电化学（循环伏安）滴定研究了所合成的识别受体在阴离子结合过程中的氧化还原性质。进行了较为全面的研究，取得了较为显著的成果，
结论摘要：
英文主题词anion recognition receptor;binding contants;nucleotide;spectrum titration
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期刊论文
Role of mononuclear rare earth metal complexes in promoting the hydrolysis of 2-hydroxypropyl p-nitr
Studies on synthesis and anion recognition properties of (3 '-nitrobenzo)[2,3-d](3"-nitrobenzo)[9,10
Mononuclear species LnL and LnLH-1 based on 1,10-phenanthroline dibenzoimidazole derivatives as cata
Dinuclear Zn2+ metal complexes based on 1,10-phenanthroline derivates as catalysts for the hydrolysi
Synthesis and crystal structure of 1-(N,N-di-(p-toluenesulfonyl))-amino-2-(N '-p-toluenesulfonyl)-am
Synthesis and anion recognition of acetate ions using pyrrole-alpha-carboxaldehyde 2,4-dinitrophenyl
Effects of the receptors bearing phenol group and copper(II) on the anion recognition and their anal
The anion binding properties of neutral receptors bearing nitro group, phenanthroline or ruthenium(I
Synthesis, characterization and biological activity of complexes of lanthanum(III) with 2-(1 '-pheny
Study of activity on anti-O2 of novel 1,10-phenanthroline bridged polyamine ligands and their comple
Study on kinetics and mechanism of mononuclear rare earth metal complexes in promoting the hydrolysi
Trinuclear metal complexes based on 1,10-phenanthroline derivates as catalysts for cleavage of a RNA
Synthesis of an anionic receptor based on phenylhydrazone group and its recognition property for ace
Colorimetric and fluorescent sensing of biologically important fluoride in physiological pH conditio
Design of two pyrazole-based sensors with similar configuration and diffeent fluorescent response to
A novel colorimetric receptor responding AcO anions based on an azo derivative in DMSO and DMSO/wate
Cobalt(III) supramolecuar complex: Synthesis, crystal structure and anions recognition properties of
A novel anion receptor employing the pyrrole and amide moieties in the cooperative binding of anions
Colorimetric and fluorogenic anionsensors of 2'-(p-nitrophenyl) imidazol[4',5'-f]-1,10-phenanthrolin
A highly selective naked-eye colorimetric sensor for acetate ion based on 1,10-phenanthroline-2,9-di
A simple colorimetric sensor for biologically important anions based on intramolecular charge transf
Rational design of a colorimetric and ratiometric fluorescent chemosensor based on intramolecular ch
A simple and efficient colorimetric anion sensor based on a thiourea group in DMSO and DMSO-water an
An optical and electrochemical anion sensor of F- investigated by UV-vis, H-1 NMR and cyclic voltamm
Study on optical recognition and electrochemical sensing of a 1,1 '-ferrocenedicarbonylhydrazine der
Kinetics and mechanism of promoted hydrolysis of 2-hydroxypropyl-p-nitrophenyl phosphate (HPNP) by c
A novel, simple, colorimetric receptor based on 2 ',4 '-dinitrophenylhydrazone for acetate ion in or
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