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中文摘要：
本项目在合成聚烯烃接枝苯乙烯的基础上，通过后交联反应合成微孔孔径、孔径分布较均匀且大小精确可控的超高交联型纤维/树脂，分析合成条件对孔结构的影响，建立合成具有分子筛效应的超高交联型纤维/树脂的方法。在此基础上，超高交联型纤维/树脂进行功能化反应，合成具有精确筛分功能、高吸附容量和高吸附选择性的多功能苯乙烯型离子交换纤维/树脂，探索产物的孔结构、表面化学结构等结构特征与溶胀性能、吸附性能等性能之间的关系规律，阐明合成条件对结构与性能的影响，进而实现小尺寸范围内尺寸不同以及尺寸相当、结构不同的小分子的同时分离，并期望在有机化工废水的治理等领域得到应用。
结论摘要：
英文主题词Molecular sieveing effect; post-crosslinking reaction; functionalization reaction; ion-exchange fiber/resin
成果综合统计
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期刊论文
Adsorption behaviors of a novel carbonyl and hydroxyl groups modified hyper-cross-linked poly(styren
Surface modification on a hyper-cross-linked polymeric adsorbent by multiple phenolic hydroxyl group
Adsorption thermodynamics of methyl orange onto a phenolic hydroxyl groups modified hyper-cross-link
Surface chemical modification on hyper-cross-linked resin by hydrophilic carbonyl and hydroxyl group
Hyper-cross-linked polystyrene-co-divinylbenzene resin modified with acetanilide: synthesis, structu
Equilibria and kinetics of phenol adsorption on a toluene-modified hyper-cross-linked poly(styrene-c
Hydroquinone modified hyper-cross-linked resin to be used as a polymeric adsorbent for adsorption of
Methylamino groups modified hyper-crosslinked polystyrene resin for removal of phenol from aqueous s
Removal of p-nitrophenol by a water-compatible hypercrosslinked resin functionalized with formaldehy
Synthesis, characterization, and adsorption properties of phenolic hydroxyl group modified hyper-cro
Treatment of phenol and p-cresol in aqueous solution by adsorption using a carbonylated hypercrossli
Tertiary amino groups modified macroporous crosslinked poly(styrene-co-divinylbenzene) and its oxidi
Application of an easily water-compatible hypercrosslinked polymeric adsorbent for efficient removal
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