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中文摘要：
针对磺化和氧化等典型"官能化"有机化工反应过程，采用理论分析、实验研究和计算机模拟相结合的方法，研究液相快速反应体系内的分子混合与传递机理、多相复杂反应体系的微纳尺度分散相的形成规律与界面传递现象、外场对化工过程传递与反应的强化机制和耦合协调规律，建立传递与反应协同作用新理论模型，应用超重力、等离子体、膜技术等强化手段，实现物质传递与反应过程的协调匹配和调控，解决反应选择性低和收率低的普遍性问题，达到典型有机化工过程节能降耗和减排的目的，并提高产品品质。创建甲烷氧化、丙酮氧化、三次采油用原油磺化等2-3个典型有机化工过程"节能减排"工业示范新技术，过程节能20%-30%。在本领域具有学术影响力的国际期刊发表系列论文，形成一支多学科交叉的具有国际学术影响的研究队伍。
英文摘要：
organic chemical engineering；transfer；reaction；match；intensification
结论摘要：
本项目围绕典型“官能化”有机化工反应体系的传递与反应协同机制及强化的关键科学问题，展开了从“科学基础—技术创新—工程化”系统性的理论和实验研究以及工业实践，深入研究了多相分子混合的机理模型、计算和实验测定方法，从微纳到宏观反应器尺度的耦合模型和高效数值计算方法，探索了超重力、等离子体、新结构膜等外场作用下对多相流的宏观/微观混合、界面传递与反应调控的影响规律，建立了液液界面微纳尺度混合/传递、超重力非连续介质混合反应、反应与膜分离过程耦合等理论模型，阐明了超重力等外场作用下的混合/传递与反应协同和调控原理，揭示了工业多相快反应体系的调控规律及反应器的工程设计基础，推进了反应工程学科在微纳尺度混合/传递与反应机制上的科学认识。在上述理论研究基础上，形成了超重力强化、等离子体强化、新结构膜强化等新工艺和技术，成功应用于12万吨/年己内酰胺超重力磺化重排、10万吨/年环己酮肟催化反应-陶瓷膜分离耦合等9条工业生产线中，典型单元过程节能30％以上，取得了显著节能减排效果，实现了项目总体科学目标，为从根源上消除化工高能耗、高污染问题，奠定了重要的理论基础，提供了强有力的技术支撑。获得国家技术发明奖二等奖2 项和国家科技进步二等奖 1 项、省部级一等奖4项、二等奖2项；共发表SCI论文225篇（AIChE J./CES/IECR三大化工顶级刊物48篇，Angew. Chem. Int. Ed./JACS/Adv. Mater. 7篇）；获得授权国际发明专利 2 件、中国发明专利 64 件；申请国际发明专利 3 件、中国发明专利 55 件；获得计算机软件著作权登记证书8项。主办及参与组织国际会议14次，国际会议大会/特邀报告55次，与国际上多所高校和跨国公司开展了广泛的学术交流与合作；入选中组部“万人计划”科技创新领军人才2人，入选国家杰出青年基金、国家百千万人才工程人选、英国皇家化学会会士各1人次，入选“教育部新世纪优秀人才支持计划” 3人；在项目承担单位北京化工大学建立了“有机无机复合材料”国家重点实验室，在南京工业大学新组建了“国家特种分离膜工程技术研究中心”；新增教育部“创新团队发展计划”创新团队1个；新增国际杂志编委16人次；培养毕业博士生49名、硕士生69名，获包括“全国百篇优秀博士学位论文”在内的多项奖励，为形成一支具有国际学术影响的创新团队奠定了基础。
成果综合统计
期刊论文
会议论文
专利
获奖
著作
期刊论文
Preparation and characterization of Co-Rh bimetallic model catalysts: From thin films to dispersed c
Crystallization of aluminium hydroxide from the reactive NaAl(OH)(4)-NaHCO3 solution: Experiment and
Influence of "Glow Discharge Plasma" as an External Stimulus on the Self-Assembly, Morphology and Bi
Adsorption and Protonation Of CO2 on Partially Hydroxylated gamma-Al2O3 Surfaces: A Density Function
Preparation of stable micro-sized crystalline irbesartan particles for the enhancement of dissolutio
Toward understanding macrocycle specificity of iron on the dioxygen-binding ability: a theoretical s
Influence of the Top Impeller Diameter on the Gas Dispersion in a Sparged Multi-impeller Stirred Tan
Particle Image Velocimetry Experiments and Large Eddy Simulations of Merging Flow Characteristics in
Particle Image Velocimetry Study of Flow Patterns and Mixing Characteristics in Multiple Impeller St
Stereoscopic PIV Experiments and Large Eddy Simulations of Flow Characteristics in Stirred Tanks wit
Absorption of Carbon Dioxide with Ionic Liquid in a Rotating Packed Bed Contactor: Mass Transfer Stu
Synthesis of Petroleum Sulfonate Surfactant by Different Sulfonating Agent with Application of HIGEE
Cobalt Schiff base with ionic substituents on ligand as an efficient catalyst for the oxidation of 4
Probing electron density of H-bonding between cation-anion of imidazolium-based ionic liquids with d
Comparison between the two different forms of iron(IV)-oxo porphyrin and the effects of neutral axia
A novel Nb2O5-doped SrCo0.8Fe0.2O3-delta oxide with high permeability and stability for oxygen separ
Highly selective hydrogenation of phenol and derivatives over a Pd@Carbon nitride catalyst in aqueou
Acetylacetone-metal catalyst modified by pyridinium salt group applied to the NHPI-catalyzed oxidati
Thermoresponsive Diblock Copolymer with Tunable Soluble-Insoluble and Soluble-Insoluble-Soluble Tran
Development of novel monolithic catalyst with porous hollow silica nanoparticles for selective hydro
PIV Experiments and Large Eddy Simulations of Merging Flow Characteristics in Dual Rushton Turbine S
Analysis of Turbulence Structure in the Stirred Tank with a Deep Hollow Blade Disc Turbine by Time-r
Effect of surface hydroxyls on selective CO2 hydrogenation over Ni-4/gamma-Al2O3: A density function
Facile and fast template removal from mesoporous MCM-41 molecular sieve using dielectric-barrier dis
Size-Controlled Synthesis of Colloidal Gold Nanoparticles at Room Temperature Under the Influence of
Effect of Pt Clusters on Methanol Adsorption and Dissociation over Perfect and Defective Anatase TiO
Special Issue of the 10th International Conference on CO2 Utilization, Tianijn, China, May 17-21, 20
Characterization of iron-containing AlPO-5 as a stable catalyst for selective catalytic reduction of
Application of HIGEE process intensification technology in synthesis of petroleum sulfonate surfacta
Numerical simulation of immiscible liquid-liquid flow in microchannels using lattice Boltzmann metho
Cobalt-site cerium doped SmxSr1-xCoO3-delta oxides as potential cathode materials for solid-oxide fu
Gating membranes for water treatment: Detection and removal of trace Pb2+ ions based on molecular re
Stimuli-responsive gating membranes responding to temperature, pH, salt concentration and anion spec
Progresses in the Preparation of Coke Resistant Ni-based Catalyst for Steam and CO2 Reforming of Met
Numerical simulation of turbulent flow in a baffled stirred tank with an explicit algebraic stress m
CFD simulation of hydrodynamics and mass transfer in an internal airlift loop reactor using a steady
Correlation analysis of the substituent electronic effects on the allylic H-abstraction in cyclohexe
Efficient CO2 Capture by Porous, Nitrogen-Doped Carbonaceous Adsorbents Derived from Task-Specific I
The influence of the inertially dominated outer region on the rheology of a dilute dispersion of low
Numerical Simulation of the Marangoni Effect on Transient Mass Transfer from Single Moving Deformabl
Ozonation of acidic phenol wastewater with O-3/Fe(II) in a rotating packed bed reactor: Optimization
Al-MCM-41 supported palladium catalyst for methane combustion: Effect of the preparation methodologi
A Superacid-Catalyzed Synthesis of Porous Membranes Based on Triazine Frameworks for CO 2 Separation
会议论文
Experimental and numerical investigation on Marangoni effect induced by mass transfer during drop fo
Equation of state for square-well chain molecules with variable range: extension to associating flui
Experimental and numerical investigation on Marangoni effect induced by mass transfer during drop fo
Experimental investigation and cfd modeling of micromixing of a single-feed semi-batch precipitation
Macromixing characteristics and bubble behaviors in an airlift internal loop reactor with low height
Effect of Fe (Ⅲ) on the Biotreatment of Bioleaching Solutions Containing Heavy Metals of Low Concent
Direct numerical simulation of methanol-steam reforming in porous media constructed randomly with la
Experimental Study and Numerical Simulation of local Void Fraction in Cold-gassed and Hot-sparged St
Mixing characteristics and bubble behavior in an airlift internal loop reactor with low height-to-di
Numerical simulation of liquid-liquid turbulent flow in a stirred tank with an explicit algebraic st
Nb2O5 improved SrCo0.8Fe0.2O3-d mixed conducting oxides for oxygen separation at intermediate temper
Direct Simulation of Influence of Pore Characteristics on Convection and Diffusion Processes in Poro
Numerical simulation of mass/heat transfer from/to a neutrally buoyant sphere in simple shear flow o
Molecular dynamics simulation on the interaction between polyelectrolyte and surfactants: effects of
Experimental investigation of micromixing of a single-feed semi-batch precipitation process in a gas
Controllable ethanol-responsive characteristics of poly(N-isopropylacrylamide)-grafted-Nylon-6 membr
Effect of surfactant on DMSO transport across water/hexane interface by molecular dynamics simulatio
Precipitation of ultra-fine manganese dioxide by coupling micro-impinging mixing with ultrasonic rea
The Mixing Behaviors in a Micro Impinging Jet Reactor and Its Application for Precipitating Ultrafin
Experimental and Computer Simulation Studies for the Adsorption Separation of CO2 from Flue Gas by 5
Understanding and Prediction of Breathing Transition in MIL-53(Al): A Thermodynamics and Statistical
Experimental studies on suspension of solid particles and power consumption in a low shear stirred v
CFD simulation of hydrodynamics, mass and heat transfer in a pilot airlift loop reactor for coal dir
Computer simulation of the adsorption and separation of CO2/CH4 and CO2/N2 in C60 Impregnated COF-10
Development of novel monolithic catalyst with porous hollow silica nanoparticles for selective hydro
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