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中文摘要：
开发和研究新型的纳米乳液体系、调控其性质是具有重要理论和实际意义的课题。超临界流体是具有许多特性的绿色溶剂。本项目采用相态观察、波谱等手段研究超临界流体对不同表面活性剂/油/水乳液体系性质和结构的调控作用，探索一类新型纳米乳液的形成条件。在此基础上，研究这类新型纳米乳液体系的宏观和微观性质与超临界流体的压力和温度、表面活性剂的结构、油水比等因素的关系，研究超临界流体诱导纳米乳液形成的规律和机理，并探索这类新型纳米乳液体系在材料制备和化学反应中的应用。这类超临界流体诱导的新型纳米乳液具有其它纳米乳液所无法比拟的优点，如纳米乳液的形成和破坏可方便地通过加压和降压进行反复控制、超临界流体可以方便地去除、有望实现对纳米乳液性质的微小调控等。此研究是涉及化学热力学、胶体与界面科学、超临界流体科学与技术等相互交叉渗透的重要课题。因此，开展相关研究不但将促进相关学科的发展，而且将拓宽超临界流体和乳液的应用范围。
结论摘要：
英文主题词nanoemulsion; supercritical fluid; property studies; formation mechanism; material synthesis
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期刊论文
One-pot synthesis of the macroporous polyaniline microspheres and Ag/polyaniline core-shell particle
Synthesis of LaCO3OH nanowires via a solvothermal process in the mixture of water and room-temperatu
Enhanced stabilization of vesicles formed in mixed cationic and anionic surfactant systems by compre
Direct measurements of the enthalpy of solution of solid solute in supercritical fluids: Study on CO
Fluorescence studies on the microenvironments of proteins in CO2-expanded reverse micellar solutions
Phase behaviors of AOT/longer chain n-alkanes reverse micelles in the presence of compressed ethylen
Preparation of silica and TiO2-SiO2 core-shell nanoparticles in water-in-oil microemulsion using com
Effect of compressed CO2 on the critical micelle concentration and aggregation number of AOT reverse
Effect of Compressed CO2 on the Chloroperoxidase catalyzed halogenation of 1,3-dihydroxybenzene in r
Controlled synthesis of Ag/TiO2 core-shell nanowires with smooth and bristled surfaces via a one-ste
Synthesis and characterization of TiO2-montmorillonite nanocomposites and their application for remo
Ru nanoparticles immobilized on montmorillonite by ionic liquids: A highly efficient heterogeneous c
Small angle X-ray scattering study on correlation length and density fluctuations in a supercritical
Why do co-solvent enhance the solubility of solutes in supercritical fluids? New evidence and opinio
Solubility of Ls-36 and Ls-45 surfactants in supercritical CO2 and loading water in the CO2/water /s
Formation of water-in-CO2 microemulsions with non-fluorous surfactant Ls-54 and solubilization of bi
Thermal decomposition kinetics and mechanism of Tb(III) m-methylbenzoate complex with 1,10-phenanthr
An investigation of non-fluorous surfactant Dynol-604 based water-in-CO2 reverse micelles by small a
Ultrasonication-induced formation of silver nanofibers in reverse micelles and small-angle X-ray sca
Effect of phase behavior, density and isothermal compressibility on the constant-volume heat capacit
Recovery of nanoparticles from (EO)8(PO)50(EO)8/p-Xylene/H2O microemulsions by tuning the temperatur
Effect of compressed CO2 on the properties of AOT reverse micelles studied by spectroscopy and phase
A novel method to load nanoparticles into mesoporous materials: Impregnation of MCM-41 with ZnS by c
Effect of compressed CO2 on the size and stability of reverse micelles: Small-angle X-ray scattering
Effects of ultrasound on the microenvironment in reverse micelles and synthesis of nanorods and nano
Synthesis of ZnS/CdS composite nanoparticles by coprecipitation from reverse micelles using CO2 as a
Investigation on the precipitation, microenvironment and recovery of protein in CO2-expanded reverse
Enhancement of the solubilization capacity of water in Triton X-100/ cyclohexane/water system by com
In situ Eu2O3 coating of the walls of mesoporous silica SBA-15 in supercritical ethane+ethanol mixtu
A novel method to synthesize polystyrene nanospheres immobilized with silver nanoparticles by compre
Preparation of polystyrene encapsulated Ag nanorods and nanofibers by combination of reverse micelle
Preparation of cadmium sulfide/poly(methyl methacrylate) composites by precipitation with compressed
Compressed CO2-enhanced solubilization of 1-butyl-3-methylimidazolium tetrafluoroborate in reverse m
A novel method to support nanocatalyst on molecular sieve-immobilization of Ru nanoparticles on SBA-
Synthesis of Ag/BSA composite nanospheres from water-in-oil microemulsion using compressed CO2 as an
Ultrasound-induced capping of polystyrene on TiO2 nanoparticles by precipitation with compressed CO2
Synthesis of uniform hollow silica spheres with ordered mesoporous shells in a CO2 induced nanoemuls
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