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中文摘要：
配位化学可通过选择适当的配体与不同的金属离子进行组装来制备具有特定功能性质的宏观物质。本项目结合申请人近年来在1,2,4-三唑类配合物方面的研究积累，根据配合物分子设计的原理（金属和配体种类多样可变，配位环境可调以及配合物组成多变），以三芳基取代的1,2,4-三唑作为配体与某些特定的金属离子自组装，来探索筛选（1）结构新颖的单核、双核及多核配合物；（2）具有高Tc和滞后回环效应的Fe(II)自旋交叉配合物；（3）具有发光性质和良好磁性的功能配合物。研究功能配合物的结构与性质间的内在关系，为寻找新材料奠定理论基础。
结论摘要：
英文主题词triazole; functional complexes; spin-crossocer; crystal structure; molecule-based materials
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期刊论文
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