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中文摘要：
在我们刚刚结题的基金项目中，首次发现了具有双磁滞回线的配合物分子磁体，这种双磁滞回线与正常的分子磁体磁滞回线有着本质的区别。在曲线形式上它与凝聚态中的反铁电体的双电滞回线十分相似。具有双电滞回线的反铁电体具有大功率的水声、超声换能和储能的功能和实际的应用价值。本课题拟以具有双磁滞回线的配合物分子磁体为研究对象。通过研究不同的形式的双磁滞回线的配合物分子磁体，搞清楚微观分子和晶体结构与宏观双磁滞回线的内在联系，尤其进一步探索双磁滞回线分子磁体的形成机制和条件。从理论上搞清楚配合物分子磁体的双磁滞回线与具有正常双S型磁滞回线分子磁体的在形成机制上的差异，以及它们的电子自旋排布方式上的区别。为有选择性地、按人为的要求去合成不同性质的分子磁体提供科学依据。另外，我们将设计、合成出具有新的结构构型的单链分子磁体2-3种。为使这一具有量子隧道效应的分子磁领域有较快的发展，增添新结构类型的成员。
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期刊论文
System-pH-dependent supermolecular isomers of puckered three-dimensioal layered hudrogen-bonded netw
Synthesis , Structure and Characters of one 3D 2-fold interpenetrating net with rare 42638 topology,
Structural and fluorescent characterizations of one- and two-dimensional Cd(II) metal-organic framew
Rarely Decorated Rutile Frameworks Built from Triangular Organic Spacers and Distorted Octahedral Co
Syntheses and crystal structures of two Cd(II) coordination polymers: one-dimensional chain
[Cd(C4H6
Self-Penetrating and Interpenetrating 3D Metal Organic-Frameworks Constructed from the Rigid 1,4-Bis
A rare Cu(I)/Cu(II)-azide complex showing honeycomb-type net structure: Synthesis, structure, and ma
Unusual T4(1) Water Chain Stabilized in the One-Dimensional Chains of a Copper(II) Coordination Poly
Synthesis and Crystal Structure of a Three-Dimensional (3D) Complex Mn(H2O)2(HNic)2 ( HNic = 2-Hydro
Synthesis and Crystal Structure of a Novel Three-Dimensional (3D) Complex Ni(Iz)2(Bdc)(H2O)2 (Iz =Im
Hydrothermal Synthesis of Metal Organic Frameworks Based on-
Aromatic Polycarboxylate and Flexible B
Decorated Rutile Net Built on the Six-connected Ln2 SBUs(secondary building units) and Three-connect
Trinuclear Cobalt Based Porous Coordination Polymers Showing Unique Topological and Magnetic Variety
A structurally stable 3D supramolecular framework with 4.0% guest-accessible void spaces that are re
Construction of microporous metal–organic frameworks (MOFs) by Mn–O–C rod-like secondary building un
A Variety of 1D to 3D Metal Organic Coordination Architectures-
Assembled with 1,1′-(2,2′-Oxybis(eth
Three Ni/Co(ΙΙ) complexes with 4,4'-bipyridine and benzoic acid derivatives as mixed coligands: Hydr
Construction of Cu(II)–Gd(III) metal–organic framework by the introduction of a small amino acid mol
Employing An Unprecedented Ferromagnetic Molecular Building Block (MBB) of [Co2Ln(μ3-OH)(CO2)5(N3)]2
An inclined interpenetrating heteropolynuclear polymer
h unusual propagation of metal carboxylate se
Synthesis and Crystal Structure of a New Dinuclear Copper(II) Polymer: [Cu2(bipy)2(Hbtc)2(H2O)2]×(H2
Construction of Lanthanide Metal-Organic Frameworks by Flexible Aliphatic Dicarboxylate Ligands Plus
Pillared 3d-4f Frameworks with Rare 3D Architecture Showing the Coexistence of Ferromagnetic and Ant
Layer-pillared metal-organic framework showing twofold interpenetration
and considerable solvent- ac
Employing Cd–O–C rod-shaped secondary building units to construct 2D metal-organic frameworks (MOFs)
A novel metal-organic coordination polymer with unprecedented floor-like structural configuration co
Hydrothermal synthesis, structure and properties of two lanthanide benzenedicarboxylates, [La2(isoph
A 3D heteropolynulear network with 4,6-connected (4462)(48668) topology: Synthesis, structure, therm
Synthesis, structure and magnetic properties of two oxo and thiocyanato-bridged manganese(II)-mercur
A novel metal-organic coordination polymer with unprecedented floor-like structural conWguration con
Employing La2- (La Eu, Tb, Pr) or Co3-Based Molecule Building) Blocks To Construct 3,8-Connected Net
A noninterpenetrating 3D coordination network with rare (4,6)-connected(4·53·62)2(42·56·64·83)topolo
One 3D noninterpenetrating metallic-organic framework with the rare (3,4)-connected (8.102)2(4.84.10
A zinc(II) coordination polymer constructed from mixed-ligand
1,2-bis(2-(1H-imidazol-1-yl)ethoxy)eth
Unprecedented (3,4)-connected metal–organic frameworks (MOFs) with 3-fold interpenetration and consi
Two 2-fold Interpenetrated Frameworks Showing Rare Topology Based on the Isomerous Benzenedicarboxyl
The Coordination Chemistry of Benzimidazole-5,6-dicarboxylic Acid with Mn(II), Ni(II), and Ln(III) C
Heteropolynuclear Metamagnet Showing Spin Canting and Single-Crystal to Single-Crystal Phase Transfo
X-ray crystal structure, spectral and magnetic properties of end-to-end di-l-thiocyanatobis(imidazol
One-Pot Synthesis of Schiff-Base-Containing Ni8 Clusters: Solvothermal Synthesis, Structure, and Mag
Syntheses and Crystal Structures of a Series of Novel Helical Coordination Polymers Constructed from
Synthesis and structural Characterization of a Novel 2D Supramolecular Complex {[Dy2Zn(dinic)4(H2O)8
Two chiral metal–organic frameworks showing unprecedented 3 pα-type topology based on the vertex-sha
Synthesis Crystal Structure and magnetic properties of two cyano-bridged copper(I) - copper(II) mixe
A 3D heteropolynuclear network with 4,6-connected (44*62)(48*66*8) topology: Synthesis, structure, t
Hydrothermal Synthesis and Crystal Structure of Heterometallic Cu/Cd Complex with H2dipic (Pyridine-
Synthesis , Structure and description of the first helical chain of Cu-Pb bimetallic atoms and coppe
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