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中文摘要：
构思设计合成具有优良发光性能和潜在应用价值的新型稀土(Tb, Eu, Sm, Dy等)芳香羧酸类功能配合物。通过元素分析、热分析、红外光谱、核磁共振谱和和单晶衍射等技术对稀土功能配合物的结构进行表征。阐明配体的配位方式和配合物的配位成键性质，从微观层次预示了配位体系的稳定性，推断可能的热解部位。用TG-DTG-IR、DSC、IR和SEM技术，首次阐明稀土功能配合物的热分解机理。用我们新提出的热分析动力学数据处理方法即双等双步法以及非线性等转化率微分法、非线性等转化率积分法和我们改进的Popescu等方法对稀土功能配合物进行动力学研究。推测标题配合物热分解反应的机理模型和相应的动力学参数热力学参数以及动力学方程和寿命方程等。用荧光仪对配合物的发光性能进行分析测试研究。通过对配合物的结构、发光性能、热分解机理及动力学等进行系统研究，可以丰富稀土配位化学的理论内容。进一步拓宽稀土元素的应用领域。
结论摘要：
英文主题词rare earth complex;structure;thermal decomposition mechanism; non-isothermal kinetics;thermochemistry
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期刊论文
Synthesis, Crystal Structure, and Thermal Properties of a Holmium(III) Benzoate Complex with 1,10-Ph
Synthesis, Crystal Structure, thermal decomposition kinetics of Sm3+ complex with p-chlorobenzoic ac
Crystal structures, luminescent properties and thermal decomposition kinetics of lanthanide complexe
Synthesis, Crystal Structure, and Thermal Decomposition Kinetics of the Complex of Ho 2,4-Dichlorobe
Synthesis and Thermochemical Properties of the Ternary Complex [Sm(m-NBA)(3)phen](2)center dot 2H(2)
Synthesis and thermal decomposition kinetics of two lanthanide complexes with cinnamic acid and 2,2'
Synthesis, crystal structure and thermal decomposition kinetics of the ternary complex [Sm(5-Cl-2-MO
Synthesis, crystal structure and properties of two ternary rare earth complexes with aromatic acid a
Synthesis, crystal structure, and properties of [Dy(p-ABA)(3)Phen center dot H2O]center dot 1.5H(2)O
Preparation, crystal structure and thermal decomposition process of dysprosium benzoate complex with
Synthesis, structures and properties of ternary rare earth complexes with fluorobenzoic acid and 1,1
Preparation and thermal decomposition reaction kinetics of a dysprosium(III) p-chlorobenzoate 1,10-p
Nonisothermal kinetics of dehydration process of [Sm(m-ClBA)3phen](2)center dot 2H(2)O and [Sm(p-ClB
Synthesis, crystal structure and thermal decomposition mechanism of the complex [Sm(p-BrBA)(3)bipy c
Preparation, structure characterization and thermal decomposition process of the dysprosium(III) m-m
Synthesis and thermal decomposition kinetics of the complexes [Sm(o-NBA)(3)bipy](2)center dot 2H(2)O
Thermal decomposition reaction kinetics of complexes of [Sm(o-MOBA)(3)bipy](2)center dot H2O and [Sm
Synthesis, structure, and antibacterial properties of ternary rare-earth complexes with o-methylbenz
Synthesis, crystal structure, luminescence and thermal decomposition kinetics of Eu(III) complex wit
Preparation, Characterization and Thermal Decomposition Kinetics of the Complexes [Dy(p-NBA)(3)Phen]
会议论文
Syntheses, crystal structures and thermal properties of two lanthanide complexes with 2,5-dichlorobe
Preparation and non-isothermal kinetics of the dehydration process of the complex of [Sm(p-MOBA)3bat
Synthesis, Crystal structure , Luminescence and thermal decomposition kinetics of Eu(Ⅲ) complex with
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