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中文摘要：
将作为中草药有效成分的五种生物碱与六种人体必需微量金属元素配位，合成系列金属-生物碱配合物，制备成单晶。用微量热法研究微量金属盐与生物碱形成配离子过程的热力学和热动力学性质。用溶解-反应量热法研究配离子的水合热和标准摩尔生成焓等参数。用红外光谱、X-射线单晶衍射法、绝热量热法、燃烧量热法和热分析等实验手段对配合物的配位特征、晶体结构、晶格能、低温热容、焓、熵、吉布斯自由能和标准摩尔生成焓等性质参数进行系统研究。用绝热量热法测定配合物在低温区发生可逆结构转变的相变温度、相变焓、相变熵等，用X-射线单晶衍射仪对相变前后结构转变机理进行深入研究。利用统计热力学方法，通过建立数学模型，将晶体结构和配位特征参数与热力学性质相关联，从理论上研究结构与热力学性质之间的关系。探明许多中医药药效的物质基础，阐明结构与药理药效的关系，为新一代复方高效无毒药物的应用开发奠定理论基础。
结论摘要：
英文主题词alkaloids; micro metal elements; coordination compound; crystal structure; Thermochemistry
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期刊论文
Investigation on Phase Transitions and Thermodynamic Properties of 1-Dodecylamine Hydrochloride (C12
Low-temperature Heat Capacities and Thermodynamic Properties of Solid State Coordination Compound Zn
Thermochemistry on the Solid State Coordination Compounds M(Nic)(2) center dot H2O(s) (M = Mn and Mg
Enthalpies of Dilution of N-Glycylglycine in Aqueous Sodium Chloride and Potassium Chloride Solution
Crystal Structure and Thermodynamic Properties of N, N-dimethylnorephedrine Hydrochloride (C11H18NOC
Low temperature heat capacities and standard molar enthalpy of formation of sodium benzoate C6H5COON
Low-Temperature Heat Capacities and Standard Molar Enthalpy of Formation of Potassium Benzoate C7H5O
Enthalpic Interactions of Formamide with D-Mannitol and D-Sorbitol in Aqueous Sodium Chloride Soluti
Synthesis, Characterization and Thermodynamic Study of the Solid State Coordination Compound Ni(Nic)
Synthesis, characterization, and thermochemistry of the solid state coordination compound Zn(Nic)(2)
Standard Molar Enthalpy of Formation of the Solid State Coordination Compound Cu(Nic)(2)center dot H
Synthesis, Characterization, and Thermodynamic Study of the Solid State Coordination Compound Cu(Nic
Low-temperature heat capacities and standard molar enthalpy of formation of N-methylnorephedrine C11
Low Temperature Heat Capacities and Thermodynamic Properties of Zinc L-Threonate Zn(C4H7O5)(2)(s) by
Synthesis, characterization, and thermodynamic study of the coordination compound Cd(HNic)(2)Cl-2(s)
Low-temperature heat capacities and standard molar enthalpy of formation of the solid-state coordina
Low-temperature heat capacities and standard molar enthalpy of formation of L-3-(3,4-dihydroxyphenyl
Low-temperature heat capacities and standard molar enthalpy of formation of chromium nicotinate Cr(C
Synthesis, Characterization, and Thermodynamic Study of the Solid State Coordination Compound Ca(Nic
Low-temperature heat capacities and thermodynamic properties of octahydrated barium dihydroxide, Ba(
Low-temperature heat capacities and thermodynamic properties of hydrated sodium cupric arsenate [NaC
Standard molar enthalpy of formation of hydrated sodium cupric arsenate [NaCuAsO4 center dot 1.5H(2)
Low-temperature heat capacity and standard molar enthalpy of formation of crystalline (S)-(+)-ibupro
Low-temperature heat capacities and thermochemistry on the complex of erbium perchlorate with L-alph
Low-temperature heat capacities and standard molar enthalpy of formation of complex Zn(Met)SO4 cente
Low-temperature heat capacities and thermodynamic properties of hydrated nickel (L)-threonate Ni(C4H
Thermochemistry on the complex of erbium perchlorate with L-alpha-glutamic acid [Er-2(L-Glu)(2)(H2O)
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