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中文摘要：
2007 年诺贝尔化学奖授予德国化学家Gerhard Ertl,以表彰他在"固体表面化学过程"研究中做出的杰出贡献。同时,固体表面化学反应在分析化学中获得了非常重要的应用。本项目拟利用分析物与固体表面相互作用或化学反应过程中产生的中间体（激发态的分子、自由基、自由原子等）、挥发性反应产物、或相互作用本身，重点开展如下研究工作: （1）基于固体表面化学反应和场辅助的发光分析方法研究; （2）固体表面低温直接化学原子化新方法研究; （3）基于固体表面催化反应的化学蒸气发生法作为光谱分析的进样技术的研究;（4） 基于固体表面相互作用的分离方法及其与光谱分析联用;（4）相关表面化学反应机理研究。提出的新方法除了部分可用作研究表面化学过程的特殊分析/表征工具以外，目标分析物主要瞄准与国家安全、人类健康密切相关的危险或有毒物质，并从实验和理论上研究其传感识别机制，进而研制相应微型光谱仪器或仪器部件。
英文摘要：
surface chemistry on solids；spectroanalysis；cataluminescence；chemcial vapor generation；signal amplification
结论摘要：
该项目主要研究了固体表面原子/分子光谱分析新方法，也涉及相关仪器部件的研制。四年来取的主要成果包括（1）建立了固体表面化学发光和场辅助（UV）化学发光分析法，如对丙酮和丙醛等挥发性有机物（VOC）在纳米材料表面的催化发光进行了系统考察，研究了其形貌对催化发光选择性的影响，并提出了基于Pd/C还原的催化发光新技术；（2）发展了基于n-Si/TiO2/TiO2:Eu和Mn掺杂ZnS量子点的二维传感技术，可用于VOC和蛋白质的识别分析；（3）提出了测定Cu，Co，Fe，Ni的新型化学蒸气发生法，设计了一种薄膜光化学反应器，极大提高了这些元素的蒸气发生效率。深入研究了固体表面快速气液分离和紫外光诱导催化（含低温原子化）反应，以及纳米材料表面分离富集-原子光谱分析的方法，并用于实际样品分析；（4）将“金标银染”等纳米粒子放大测量应用于免疫分析，建立了基于ICP-MS和HG-AFS的蛋白质定量新方法；（5）开展了一些基于介质阻挡放电和电晕放电光谱分析的相关研究，并初步探索了火花放电应用于元素成像分析的可行性。
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期刊论文
A sensitive and specific enzyme-linked immunosorbent assay for the detection of lincomycin in food s
Molecular dynamics and density functional theory studies of substrate binding and catalysis of human
High-Yield UV-Photochemical Vapor Generation of Iron for Sample Introduction with Inductively Couple
Simultaneous stacking of cationic and anionic compounds in single run capillary zone electrophoresis
Ultrasensitive determination of cobalt in single hair by capillary electrophoresis using chemilumine
Theoretical Investigations on the Mechanism of Benzoin Condensation Catalyzed by Pyrido 1,2-a -2-eth
Mechanism for the Reaction of 2-Naphthol with N-Methyl-N-phenyl-hydrazine Suggested by the Density F
Ultrasensitive determination of selenium by atomic fluorescence spectrometry using nano-TiO2 pre-con
Theoretical studies on the chemical decomposition of 5-aza-2 '-deoxycytidine: DFT study and Monte Ca
Simple mercury speciation analysis by CVG-ICP-MS following TMAH pre-treatment and microwave-assisted
Dielectric Barrier Discharge Molecular Emission Spectrometer as Multichannel GC Detector for Halohyd
Quantum mechanics study and Monte Carlo simulation on the hydrolytic deamination of 5-methylcytosine
Ultrasensitive fluorescence detection of glutaraldehyde in water samples with bovine serum albumin-A
A potential visual fluorescence probe for ultratrace arsenic (III) detection by using glutathione-ca
UV-Induced Surface Photovoltage and Photoluminescence on n-Si/TiO(2)/TiO(2):Eu for Dual-Channel Sens
Vapor generation in dielectric barrier discharge for sensitive detection of mercury by inductively c
Establishment of an immunoaffinity chromatography for simultaneously selective extraction of Sudan I
Applications of chemical vapor generation in non-tetrahydroborate media to analytical atomic spectro
Mechanism Insight into the Cyanide-Catalyzed Benzoin Condensation: A Density Functional Theory Study
In Silico Prediction and Screening of gamma-Secretase Inhibitors by Molecular Descriptors and Machin
Theoretical Investigations on the Thermal Decomposition Mechanism of 5-Hydroxy-6-hydroperoxy-5,6-dih
Determination of ultratrace nitrogen in pure argon gas by dielectric barrier discharge-molecular emi
Theoretical Studies on the Thermodynamics and Kinetics of the N-Glycosidic Bond Cleavage in Deoxythy
Effects of Substituent and Leaving Group on the Gas-Phase S(N)2 Reactions of Phenoxides with Halomet
Theoretical Studies on the Water-Assisted Hydrolysis of N,N-Dimethyl-N '-(2 ',3 '-dideoxy-3 '-thiacy
Light emitting diode induced chemiluminescence and its application as a detector for high performanc
THE INFLUENCES OF OXIDATION AND CATIONIZATION ON THE N-GLYCOSIDIC BOND STABILITY OF 8-OXO-2 '-DEOXYA
Thermal catalysis induced chemiluminescence and its application for determination of volatile chlori
Highly sensitive and specific determination of mercury(II) ion in water, food and cosmetic samples w
Highly sensitive and specific detection of neonicotinoid insecticide imidacloprid in environmental a
Preparation and characterization of molecularly imprinted microspheres for selective extraction of t
Ultrasensitive determination of cobalt and nickel by atomic fluorescence spectrometry using APDC enh
Recent Advance of Hydride Generation-Analytical Atomic Spectrometry: Part II-Analysis of Real Sample
Direct detection of 3-amino-5-methylmorpholino-2-oxazolidinone (AMOZ) in food samples without deriva
Protein Quantitation Using Ru-NHS Ester Tagging and Isotope Dilution High-Pressure Liquid Chromatogr
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