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中文摘要：
本项目提出利用动态共价键化学的原理，通过控制芳酰胺寡聚体或其片段的预组织构象，发展构筑大环分子的新方法。利用分子内氢键诱导寡聚芳酰胺采取"之"字型构象，在骨架的一侧重复引入醛基、氨基或单酰肼等官能团，通过长度匹配的单体中氨基和单酰肼与醛基形成C=N键的可逆反应特征，实现热力学控制的大环、双环和多环分子的形成。在芳酰胺片段的两侧并入两个反应位点，通过其预组织构象诱导结构匹配的前体组装产生稳定的亚胺穴状分子，实现双层穴状分子的一步高效合成。在上述设想基础上，进一步验证不同系列的多组分前体通过自我分类实现各自选择性成环的可能性，探索手性穴状结构的选择性形成及新的环结构体系在分子识别及自组装研究中的应用等。
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期刊论文
Hydrogen bonding-mediated foldamer-bridged zinc porphyrin- C60 dyads. ideal face-to-face orientation
Intramolecular Six- Membered and Three-Center C(H(((O Hydrogen Bonding in 1,4-Diphenyl- 1,2,3-Triazo
Hydrogen Bonded Supramolecular Polymers in Both Apolar and Aqueous Media: Assembly and Reversible Co
Controllable Self-Assemblies of Nanotubes and Vesicles from Arylamides and Their Applications as Tem
Dynamic Covalent Self-Assembly of Mono-, Bi- and Trimacrocycles from Hydrogen Bonded Preorganized Te
Construction of Microbelts through the Co-Assembly of a Disc-Like Molecule and Primary Alkyl Ammoniu
Self-Assembly of Vesicles by a 2,6-Di((7-benzamidy)quinolin-2-yl) pyridine Derivative Tuned by an Am
Tunable Coordinative Assembly of a Disclike Molecule and Metal Ions: from Microspheres to Microtubes
Hydrogen Bonding- Directed Quantitative Self-Assembly of Cyclotriveratrylene Capsules and Their Effi
Reverse vesicles formed by hydrogen bonded arylamide-derived triammonium cyclophanes and hexaammoniu
Hydrogen Bonded Foldamer- Bridged Biscoumarins. A UV-Vis Absorption and Fluorescent Study of the Sol
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