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中文摘要：
本项目将研究环三聚藜芦烯超分子金属络合物的分子设计，纳米组装和催化反应。设计合成一系列结构新颖的环三聚藜芦烯功能分子和多齿配体。建立环三聚藜芦烯功能化修饰的简洁实用途径，拓展功能化环三聚藜芦烯在超分子化学中的应用范围。制备亚胺、茂环、多硫和氮杂卡宾等多种类型的多核金属络合物。建立以环三聚藜芦烯为平台的多核金属络合物的合理合成方法，研究所合成的多合金属络合物的分子结构、晶体结构、光谱性质及电化学性质。探索环三聚藜芦烯金属络合物在典型有机合成反应中的催化作用。特别关注手性环三聚藜芦烯金属络合物的合成和性质研究。通过环三聚藜芦烯超分子配体- - 金属配位键作用，自组装成低对称性、开放结构的大尺寸的多功能化金属纳米体系。通过对两亲性环三聚藜芦烯功能分子溶液性质和自组装性质的研究，研究受环三聚藜芦烯保护的贵金属纳米粒子体系的制备和催化作用。
英文摘要：
cyclotriveratrylene；metal complex；self-assembly；nano materail；multicomponent reaction
结论摘要：
本国家自然科学基金项目《环三聚藜芦烯超分子金属络合物的分子设计，纳米组装和催化性质的研究》项目获立项以来，在2010-2012年度，按照项目申请书和任务书确定的研究计划，开展了系统的研究工作，研究工作基本按照原确定计划和方案进行，在环三聚藜芦烯型杯芳烃的功能化修饰方法，杯芳烃多齿配体和金属络合物的制备，杯芳烃功能分子的自组装，纳米材料的制备和性能等方面进行了深入细致的已经工作，通过精心设计的合成路线合成了大量的含多种配位功能和分子识别功能的新型杯芳烃主体分子。详细研究了各种杯芳烃主体分子和过渡金属离子的配位作用，得到了一系列结构新颖的杯芳烃过渡金属络合物。将环三聚藜芦烯型杯芳烃功能分子作为金属纳米粒子的模板和保护剂，制备了一系列稳定分散的贵金属纳米离子体系，设计了几个新的多组分反应，为含氮杂环化合物提供了新的简洁合成方法。全面完成了立项确定的研究目标。取得了一些有价值的研究成果，完成了立项确定的研究目标。已经发表研究论文31篇，全部被SCI收录，其中IF > 3.0 的17篇，IF > 2.0的4篇。还有一些研究结果正在整理发表过程中。
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期刊论文
Preparation of Resorcinarene-Functionalized Gold Nanoparticles and Their Catalytic Activities for Re
Synthesis of Polysubstituted Dihydropyridines by Four-Component Reactions of Aromatic Aldehydes, Mal
Molecular Diversity of Three-Component Reactions of N-Benzylbenzimidazolium Salts, Isatin, and Malon
Diastereoselective Synthesis of trans-2,3-Dihydrothiophenes via Multicomponent Reactions of Pivaloyl
Efficient synthesis of polysubstituted pyrrole-3-carbonitriles via reactions of 1,1-dicyano-2,3-diar
Convenient synthesis of polyfunctional dihydrothiophenes with tandem reaction of 1,3-thiazolidinedio
Molecular Diversity of the Three-Component Reactions of N-Benzylbenzimidazolium Salts, Aromatic Alde
Synthesis of Spiro Dihydrofurans and 1,8-Dioxo-xanthenes via DABCO Catalyzed Tandem Reaction of Alde
Molecular Diversity of Three-Component Reactions of Aromatic Aldehydes, Arylamines, and Acetylenedic
Hydrothermal syntheses, structures and luminescent properties of Zn(II) coordination polymers assemb
Synthesis of ammonium S-S bond linked dipyridinedionates via four-component reactions of cyanoacetam
Three-component Reaction of Aromatic Aldehyde, Malononitrile and Aliphatic Amine Leading to Differen
Novel synthesis of resorcinarene O-acetates by BF3 center dot OEt2-catalyzed cyclocondensation of 1,
Synthesis of Zwitterionic Salts or Pyridinium-Meldrum Acid and Barbiturate through Unique Four-compo
Diastereoselective Synthesis of trans-2,3,6,7-Tetrahydro-4(5H)-benzofuranones and trans-2,3-Dihydrof
Microwave Assisted Synthesis of 3,3 ';,3 ';';,3 ';';';-o-, p-Phenylenedimethylidinetetrakis-(4-hydro
Syntheses, reactions and crystal structures of 1,3-alternate p-tert-butylthiacalix[4]arene esters an
Synthesis of zwitterionic salts via three component reactions of nitrogen-containing heterocycles, a
Selective Synthesis of Fused 1,4-and 1,2-Dihydropyridines by Domino Reactions of Arylamines, Acetyle
Synthesis of Functionalized Thiophenes by Four-component Reactions of 1,3-Thiazolidinedione, Aromati
Synthesis of 3,4-Dihydropyridin-2(1H)-ones and 3,4-Dihydro-2H-pyrans via Four-Component Reactions of
Synthesis of Functionalized 2-Aminohydropyridines and 2-Pyridinones via Domino Reactions of Arylamin
One-pot two-step tandem reactions for selective synthesis of pyrrolo[2,1-a]isoquinolines and dihydro
Synthesis of zwitterionic salts via three-component reactions of pyridacylpyridinum iodide, aromatic
The unprecedented C-alkylation and tandem C-/O-alkylation of phenanthrolinium salts with cyclic 1,3-
Efficient Construction and Structure Determination of Novel Macrocycles with Calixarene Bishydrazone
Syntheses and structures of Mn(II), Co(II), and Zn(II) complexes of 1,3-diterpyridyl-substituted p-t
One-pot synthesis of 4-substituted isoquinolinium zwitterionic salts by metal-free C-H bond activati
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