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中文摘要：
本项目拟以炔烃芳构化反应和贫电子炔烃的异构化反应为模型反应，分别采用聚合物固相负载的金属催化剂和有机催化剂，通过超临界二氧化碳和常规有机溶剂中两类反应的对比考察，探索两类反应在超临界二氧化碳中使用聚合物负载催化技术的规律性，寻找可应用于超临界二氧化碳中聚合物负载催化剂的种类与有效方式，发展有机合成反应的新方法、新技术。本项目还结合超临界二氧化碳介质与固相负载催化剂两者的优点，高效地实现产物的分离、催化剂的回收再利用，使有机合成反应更绿色化、更高效。因此，开展此项技术的研究无疑具有重要的理论与实际意义。
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期刊论文
Water as a direct hydrogen donor in supercritical carbon dioxide: A novel and efficient Zn-H2O-CO2 s
Efficient electrochemical synthesis of 2-arylsuccinic acids from CO2 and aryl-substituted alkenes wi
Efficient synthesis of (-oxopropylcarbamates in compressed CO2 without any additional catalyst and s
Development, scope and mechanisms of multicomponent reactions of asymmetric electron-deficient alkyn
Polymer-supported tertiaryphosphine (JJ-TPP) as a green and recyclable organocatalyst for α-addition
Synthesis of vicinal diamines via Zn–H2O–CO2-induced reduction of aromatic imines in supercritical c
Polystyrene-supported phenol/ DMAP: An efficient binary catalyst system for CO2 fixation to give cyc
PdCl2-catalyzed heterocyclotrimerization in MeOH/scCO2: A versatile approach to dimethyl pyridine-3,
Pd(II)-catalyzed acetalization of terminal olefins with electron-withdrawing groups in supercritical
An efficient and practical process for Pd/Cu cocatalyzed homo- coupling reaction of terminal alkynes
Highly efficient three-component synthesis of polysubstituted 2, 5-dihydro-1,3-oxazin-6-ones under m
Synthesis of phthalides via Pd/CNTs-catalyzed reaction of terminal alkynes and o-iodobenzoic acid un
A facile method for the epoxidatiuaon of cyclic enone catalyzed by tert-BuNH2 with 30% hydrogen pero
Carbon nanotubes-supported palladium nanoparticles for the Suzuki reaction in supercritical carbon d
Protonolysis of the carbon-palladium bond in palladium (II)-catalyzed enyne cyclization in imidazoli
Efficient electrochemical dicarboxylations of arylacetylenes with carbon dioxide using nickel as the
Naturally occurring α-amino acid catalyzed coupling of carbon dioxide with epoxides to afford cyclic
Convenient one-pot synthesis of multisubstituted tetrahydropyri- midines via catalyst-free multicomp
Palladium- catalyzed enyne cyclization of 2’-alkenyl 2- alkynoates in imidazolium-type ionic liquids
Copper-catalyzed cross-coupling reaction of bromoslkynols with terminal alkynes in supercritical car
Palladium-catalyzed C–N bond activation: The synthesis of β-amino acid derivatives from triethylamin
Palladium-catalyzed allylation of alkynes with allyl alcohol in aqueous media: highly regio- and ste
Solvent-free heterogeneous orga- nocatalysis: Stereoselective isom- erization of α,β-ynones to (E, E
Palladium-catalyzed cleavage reaction of carbon-carbon triple bond with molecular oxygen promoted by
First synthesis of 1-chlorovinyl allenes via palladium-catalyzed allenylation of alkynoates with pro
Silver-catalyzed activation of internal propargylic alcohols in supercritical carbon dioxide: effici
One-pot three-component synthesis of pyrazoles through a tandem coupling- cyclocondensation sequence
An efficient and eco-friendly process for conversion of carbon dioxide to oxazolones and oxazolidino
会议论文
Polystyrene-supported amino acids: Heterogeneous catalysts for the coupling of carbon dioxide with e
A highly regioselective synthesis of pyrimidine derivatives via multicomponent reaction of alkynoate
Allenylation of alkynes in aqueous phase: First facile synthesis of chloro-substituted ene-allene de
Immobilizing L-histidine on mesoporous MCM-41 as a heterogeneous catalyst for the synthesis of propy
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