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中文摘要：
本项目基于对称或不对称席夫碱配体以及一些含氮、氧杂环有机配体，在常规溶液反应条件下或溶剂热或水热反应条件下，和金属盐类或氧化物反应组装得到一系列结构新颖的、具有一定荧光性能或磁学性能或生物活性的金属有机配合物，对于一些反应体系我们还较为系统地研究了反应条件和金属有机配合物的结构与性能之间的构效关系，发现了一些构筑规律。利用局部反应手段- - -单晶到单晶的转化策略，我们实现了不同晶体间的转化，为不易直接合成的新金属配合物提供了一条有效的途径。在反应过程中我们还发现了，酸催化或促进的席夫碱配体的部分水解反应也是不对称席夫碱金属配合物的一条有效的合成途径。在基于吡啶羧酸配体的金属有机框架(MOFs)配合物的构筑过程中，我们发现不仅螺旋特征普遍存在，而且有些框架结构具有很好的气体吸附性能。
结论摘要：
英文主题词Azo-heterocyclic organometallic complexes; structure; fluorescent propeties, biological activity; helical character
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期刊论文
Auxiliary Ligand-Dependent Assembly of Several Ni/Ni-Cd Compounds with N2O2 Donor Tetradentate Symme
Assembly of a Series of Trinuclear Zinc(II) Compounds with N2O2 Donor Tetradentate Symmetrical Schif
Syntheses and conversions of dinuclear cadmium(II) compounds containing N2O/N2O2 donor tridentate/te
Construction of three high-dimensional supramolecular networks from temperature-driven conformationa
Syntheses, characterization, and luminescence of two lanthanide complexes [Ln(2)(acetate)(6)(H2O)(4)
Synthesis and characterization of bis(methyl-2-pyridylmethylidenedrazinecarbodithioate)manganese(II)
Efficient synthesis of novel six-member ring-fused quinoline derivatives via the Friedlander reactio
One-, Two-, and Three-Dimensional Lanthanide Complexes Constructed from Pyridine-2,6-dicarboxylic Ac
Construction of Three-Dimensional Metal-Organic Frameworks with Helical Character through Coordinati
Synthesis, crystal structures and photoluminescence of Zn-Ln heterometallic polymers based on pyridi
Temperature- and solvent-controlled dimensionality in a zinc 6-(1H-benzoimidazol-2-yl)pyridinecarbox
Synthesis and characterization of two temperature-dependent copper(II) complexes based on 2,6-dimeth
Metal-directed assembly of two 2-D 4d-4f coordination polymers based on elliptical triple-deck cylin
Construction of Zn-II-based rac-Helical Chains Containing Semi-rigid Dipolar Ligand 1,4-Bis(benzimid
Highly enantio- and diastereoselective synthesis of alpha-trifluoromethyldihydropyrans using a novel
Syntheses and characterization of three lanthanide(III) complexes containing pyridine-3,5-dicarboxyl
Puckered-boat conformation (H2O)(14) cluster on the self-assembly of an inorganic-metal-architecture
Synthesis, crystal structure and biological activity of 2-[2-(quinolin-2-yl)vinyl]-8-hydroxyquinolin
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