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中文摘要：
利用原子-分子反应实验装置、低温变温表面反应装置、原位反应原位探测实验装置，开展活性卤素化学反应过程和机制研究。利用瞬变能谱-质谱、激光光电离质谱、时间分辨激光光谱实验手段研究短寿命活性卤素物种组成、结构与化学反应性质。结合实验和量子化学理论计算研究深入开展活性卤素复杂反应和演变过程研究。重点研究活性卤素气相光化学、低温反应和演变过程、异相反应过程和机制。对活性卤素物种及其参与反应的深入系统的实验室研究，将为其环境化学过程及其环境效应的直接观测和模式研究提供重要的实验室研究基础和依据。也将为发现抑制或减缓这些物种以及人类和天然排放物对大气臭氧破坏的新思路、新途径提供重要理论基础。
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期刊论文
Ab initio and DFT study of the structural properties and thermochemistry of CH3S(O)2OONO2 atmospheri
A HeI photoelectron spectroscopy and theoretical study of 2,6-dichloropyrazine, 2,3-dichloropyrazine
Evidence of the formation and conversion of unstable thionyl isocyanate: Gas-phase spectroscopic stu
Photoelectron spectroscopy (PES), photoionization mass spectroscopy (PIMS), and theoretical investig
Gas-phase generation, structure, spectroscopy, and quantum chemical calculations of fluorocarbonylsu
Experimental and theoretical study of two novel thioperoxides: Methoxycarbonylsulfenyl acetate, CH3O
Experimental and theoretical study of the electronic structureof methyl chloroformate and methyl cya
Experimental and theoretical studies on the electronic properties of acetyl pseudohalides CH3C(O)X (
Bis(trifluoroaceto) Disulfide (CF3C(O)OS-SOC(O)CF3): A HeI Photoelectron Spectroscopy and Theoretica
He I Photoelectron Spectroscopy and Theoretical Investigation on Diaceto Disulfide, CH3C(O)OSSOC(O)C
A novel thioperoxide, chlorocarbonylsulfenyl acetate, ClC(O)SOC(O)CH3: Characterized by HeI photoele
Electronic Structure and Photoionization and Dissociation Processes of Bis(trifluoromethoxy) disulfu
He I photoelectron spectroscopy and quantum chemical investigation on trichloromethanesulfenyl benzo
Study on the atmospheric photochemical reaction of CF3 radica using ultraviolet photoelectron and ph
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