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中文摘要：
"推动能源生产和利用方式变革"是十二五规划中具有重大战略意义的课题之一。 太阳能的重要利用方式之一是研制成本较低、效率较高和无污染的染料敏化太阳能电池（DSSC）。其中，电解质的主要功能是复原染料和传输电荷，它是影响DSSC光电转化效率和长期稳定性的重要因素之一，目前广泛采用的碘电对有强腐蚀性，且不利于封装，与染料能级匹配不好，严重限制了DSSC开路电压的提高，因此开发与电池各组分能级匹配的新型高效非碘电解质是提高DSSC光电转换效率所亟待解决的问题。由于多酸结构多样，溶解性和稳定性好，氧化还原活性高，本身可被还原成杂多蓝，可与其氧化型多酸组成氧化还原电对构筑DSSC电解质。本课题首次以氧化型和还原型多酸为非碘电对构筑DSSC的电解质，克服碘电对缺点，提高DSSC的光电转化效率。多酸型非碘电对是一项具有重大意义的创新性课题，未见报道，将为解决能源危机和环境污染等重大问题提供新的途径。
结论摘要：
英文主题词Iodine-free couples；polyoxometalates；dye-sensitized solar cells；electrolytes；photoelectric properties
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期刊论文
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A strategy for breaking the MOF template to obtain small-sized and highly dispersive polyoxometalate
Polyoxometalate/TiO2 Interfacial Layer with the Function of Accelerating Electron Transfer and Retar
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